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814006 tert-Butyl hydroperoxide

(70% solution in water) for synthesis

tert-Butyl hydroperoxide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
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814006
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8140060005
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      		 Glass bottle 5 ml
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      8140060250
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          		 Plastic bottle 250 ml
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          Description
          Catalogue Number814006
          References
          Product Information
          HS Code2909 60 12
          Structure formula ImageStructure formula Image
          Quality LevelMQ200
          Applications
          Biological Information
          Physicochemical Information
          Boiling point37 °C (20 hPa)
          Density0.94 g/cm3 (20 °C)
          Flash point38 °C
          Melting Point-3 °C
          Vapor pressure232 hPa (60 °C)
          Refractive Index1.3870 (20 °C)
          Solubility130 - 150 g/l
          Dimensions
          Materials Information
          Toxicological Information
          LD 50 oralLD50 Rat 810 mg/kg
          LD 50 dermalLD50 Rabbit 628 mg/kg
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H226: Flammable liquid and vapour.
          H242: Heating may cause a fire.
          H302: Harmful if swallowed.
          H311: Toxic in contact with skin.
          H314: Causes severe skin burns and eye damage.
          H317: May cause an allergic skin reaction.
          H330: Fatal if inhaled.
          H335: May cause respiratory irritation.
          H341: Suspected of causing genetic defects.
          H411: Toxic to aquatic life with long lasting effects.
          EUH044: Risk of explosion if heated under confinement.
          Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
          P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
          Signal WordDanger
          Storage class5.2 Organic peroxides and self-reacting hazardous materials
          WGKWGK 3 highly hazardous to water
          Disposal10
          Organic peroxides can be detected in aqueous solutions or organic solvents using the Perex-Test® (Cat. No. 116206). Pure peroxides are diluted to min. 10% in a suitable solvent or with water and added in small portions, with temperature control, to iron(II) chloride (Cat. No. 103860) solution. Test for complete reaction with the Perex-Test® (Cat. No. 116206). Container D. Explosive substances (storage class 4.1A) should be packed separately and tightly sealed for disposal. Ensure sufficient phlegmatization by water or the stated phlegmatizing agent!
          Safety Information
          Categories of dangeroxidizing, flammable, harmful, corrosive, sensitizing, dangerous for the environment
          Product Usage Statements
          Storage and Shipping Information
          StorageStore at +15°C to +25°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 3109 , 5.2 (8),
          Declaration (transport by air) IATA-DGRUN 3109 , 5.2 (8),
          Declaration (transport by sea) IMDG-CodeUN 3109 , 5.2 (8),
          Supplemental Information
          Specifications
          Assay (iodometric)67.0 - 73.0 %
          Density (d 20 °C/ 4 °C)0.937 - 0.938
          Global Trade Item Number
          Catalogue Number GTIN
          8140060005 04022536404400
          8140060250 04022536404417

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          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Oxidation Reagents
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Carboxylic Acid Derivatives > Other Carboxylic Acid Derivatives > Peracids and Peroxides