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814006 tert-Butyl hydroperoxide

(70% solution in water) for synthesis

tert-Butyl hydroperoxide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
814006
Purchase on Sigma-Aldrich

Overview

Replacement Information

Products

Catalogue NumberPackaging Qty/Pack
8140060005 Glass bottle 5 ml
8140060250 Plastic bottle 250 ml
Description
Catalogue Number814006
References
Product Information
HS Code2909 60 90
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Biological Information
Physicochemical Information
Boiling point37 °C (20 hPa)
Density0.94 g/cm3 (20 °C)
Flash point38 °C
Melting Point-3 °C
Vapor pressure232 hPa (60 °C)
Refractive Index1.3870 (20 °C)
Solubility130 - 150 g/l
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 810 mg/kg
LD 50 dermalLD50 Rabbit 628 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H226: Flammable liquid and vapour.
H242: Heating may cause a fire.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H330: Fatal if inhaled.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H411: Toxic to aquatic life with long lasting effects.
EUH044: Risk of explosion if heated under confinement.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Signal WordDanger
Storage class5.2 Organic peroxides and self-reacting hazardous materials
WGKWGK 3 highly hazardous to water
Disposal10
Organic peroxides can be detected in aqueous solutions or organic solvents using the Perex-Test® (Cat. No. 116206). Pure peroxides are diluted to min. 10% in a suitable solvent or with water and added in small portions, with temperature control, to iron(II) chloride (Cat. No. 103860) solution. Test for complete reaction with the Perex-Test® (Cat. No. 116206). Container D. Explosive substances (storage class 4.1A) should be packed separately and tightly sealed for disposal. Ensure sufficient phlegmatization by water or the stated phlegmatizing agent!
Safety Information
Categories of dangeroxidizing, flammable, harmful, corrosive, sensitizing, dangerous for the environment
Product Usage Statements
Storage and Shipping Information
StorageStore at +15°C to +25°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 3109 , 5.2 (8),
Declaration (transport by air) IATA-DGRUN 3109 , 5.2 (8),
Declaration (transport by sea) IMDG-CodeUN 3109 , 5.2 (8),
Supplemental Information
Specifications
Assay (iodometric)67.0 - 73.0 %
Density (d 20 °C/ 4 °C)0.937 - 0.938
Global Trade Item Number
Catalogue Number GTIN
8140060005 04022536404400
8140060250 04022536404417

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Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Polymerization Reagents > Polymerization, Initiators
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Oxidation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Carboxylic Acid Derivatives > Other Carboxylic Acid Derivatives > Peracids and Peroxides
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Oxidation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Carboxylic Acid Derivatives > Other Carboxylic Acid Derivatives > Peracids and Peroxides