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805660 Lithium

805660
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
7439-93-2231-102-5LiLi6.94 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8056600010 Glass bottle 10 g
8056600025 Glass bottle 25 g
8056600100 Glass bottle 100 g
Description
Catalogue Number805660
DescriptionLithium
References
Product Information
CAS number7439-93-2
EC index number003-001-00-4
EC number231-102-5
Hill FormulaLi
Chemical formulaLi
Molar Mass6.94 g/mol
HS Code2805 19 90
Quality LevelMQ200
Applications
ApplicationLithium (sticks) (protective liquid: paraffin oil) for synthesis. CAS 7439-93-2, EC Number 231-102-5, chemical formula Li.
Biological Information
Physicochemical Information
Density0.534 g/cm3
Melting Point180 °C
Vapor pressure1 hPa (723 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
Precautionary Statement(s)P223: Do not allow contact with water.
P231 + P232: Handle and store contents under inert gas. Protect from moisture.
P260: Do not breathe dust.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.
Signal WordDanger
Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 1 slightly hazardous to water
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Categories of dangerhighly flammable, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1415 , 4.3, I
Declaration (transport by air) IATA-DGRUN 1415 , 4.3, I
Declaration (transport by sea) IMDG-CodeUN 1415 , 4.3, I
Supplemental Information
Specifications
Assay of Li≥ 99.0 %
Global Trade Item Number
Catalogue Number GTIN
8056600010 04027269276898
8056600025 04022536387031
8056600100 04022536387048