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818308 (-)-Brucine

818308
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
357-57-3206-614-7C₂₃H₂₆N₂O₄394.47 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8183080050 Plastic bottle 50 g
Description
Catalogue Number818308
Synonyms2,3-Dimethoxy strychnine
References
Product Information
CAS number357-57-3
EC index number614-006-00-1
EC number206-614-7
Hill FormulaC₂₃H₂₆N₂O₄
Molar Mass394.47 g/mol
HS Code2939 79 90
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Application(-)-Brucine for resolution of racemates for synthesis. CAS 357-57-3, molar mass 394.47 g/mol.
Biological Information
Physicochemical Information
Boiling point470 °C
Melting Point175 - 178 °C
Bulk density230 kg/m3
Solubility3.2 g/l slightly soluble
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Statement(s)H300 + H330: Fatal if swallowed or if inhaled.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s)P260: Do not breathe dust.
P264: Wash skin thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P284: Wear respiratory protection.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
Signal WordDanger
RTECSEH8925000
Storage class6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3 highly hazardous to water
Disposal9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Safety Information
Categories of dangervery toxic, dangerous for the environment
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1570 , 6.1, I
Declaration (transport by air) IATA-DGRUN 1570 , 6.1, I
Declaration (transport by sea) IMDG-CodeUN 1570 , 6.1, I
Supplemental Information
Specifications
Assay (HClO₄)≥ 98.0 %
Melting range (lower value)≥ 173 °C
Melting range (upper value)≤ 178 °C
Spec. rotation [α²0/D (c=1 in ethanol)-86.0 - -80.0 °
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8183080050 04022536432786

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Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Phenols and Phenol Ethers > Phenolcarboxylic Acids and Derivatives
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Phenols and Phenol Ethers > Phenolcarboxylic Acids and Derivatives
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Products for Enantioselective Synthesis > Reagents for Resolving Racemates
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Enantioselective Synthesis > Reagents for Resolving Racemates
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Phenols and Phenol Ethers > Phenolcarboxylic Acids and Derivatives
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Enantioselective Synthesis > Reagents for Resolving Racemates