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100720 Sulfuric acid fuming 65% SO₃

EMPLURA®

Synonyms: Oleum

100720
Purchase on Sigma-Aldrich

Overview

Replacement Information

Products

Catalogue NumberPackaging Qty/Pack
1.00720.1002 Glass btl. pl.coat. 1 l
Description
Catalogue Number100720
SynonymsOleum
DescriptionSulfuric acid fuming 65% SO₃
References
Product Information
CAS number8014-95-7
EC index number016-019-00-2
EC number231-976-8
Hill FormulaH₂O₄S*SO₃ (1:2)
Chemical formulaH₂SO₄*SO₃ (1:2)
Molar Mass258.20 g/mol
HS Code2807 00 10
Quality LevelMQ200
Applications
Biological Information
Physicochemical Information
Boiling point64 °C (1013 hPa)
Density1.99 g/cm3 (20 °C)
Melting Point1 °C
pH value1 (100 g/l, H₂O, 20 °C)
Vapor pressure105 hPa (20 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
EUH014: Reacts violently with water.
Precautionary Statement(s)P234: Keep only in original packaging.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
RTECSWS5605000
Storage class6.1B Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 1 slightly hazardous to water
Disposal12
Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.
Safety Information
Categories of dangercorrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1831 , 8 (6.1), I
Declaration (transport by air) IATA-DGRUN 1831 , 8 (6.1),
Declaration (transport by sea) IMDG-CodeUN 1831 , 8 (6.1), I, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Color (visual)colourless to brownish
Appearance of substance (visual)clear to turbid
Content of free SO₃ (acidimetric)64 - 66 %
Residue on ignition≤ 0.02 %
the product may be present as a cloudy viscous liquid and form fine suspended particles
The product may be present as a cloudy viscous liquid and form fine suspended particles
Global Trade Item Number
Catalogue Number GTIN
1.00720.1002 04054839995453

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