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109164 Hanus solution

for determination of iodine number c(IBr) = 0.1 mol/l Titripur®

Hanus solution MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Iodine solution acc. to Hanus

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109164
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Overview

Replacement Information

Products

Catalogue NumberPackaging Qty/Pack
1.09164.1000 Glass bottle 1 l
1.09164.1003 Glass bottle 1 l
Description
Catalogue Number109164
SynonymsIodine solution acc. to Hanus
References
Product Information
HS Code3822 19 90
Quality LevelMQ200
Applications
Biological Information
Physicochemical Information
Density1.06 g/cm3 (20 °C)
Flash point40 °C
pH value<1 (H₂O, 20 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H226: Flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
Storage class3 Flammable liquids
WGKWGK 2 obviously hazardous to water
Disposal12
Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.
Safety Information
Categories of dangerflammable, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore at +15°C to +25°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2789 , 8 (3), II
Declaration (transport by air) IATA-DGRUN 2789 , 8 (3), II
Declaration (transport by sea) IMDG-CodeUN 2789 , 8 (3), II, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Formliquid
Amount-of-substance concentration0.0994 - 0.1006 mol/l
Measurement uncertainty+/- 0.0004
TraceabilityNIST SRM
The stated batch and specification values for the amount of substance concentration are valid at the time of bottling.
The amount-of-substance concentration of this volumetric solution is analyzed by our quality control laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025.
The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is determined with standardized sodium thiosulfate solution (article number 1.09147). The sodium thiosulfate solution is standardized and traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 136 potassium dichromate) by means of volumetric standard potassium iodate (article number 1.02404), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.
Note: The concentration of this volumetric solution decreases over time, due to its chemical properties. If high accuracy is expected, the titer, being a corrective factor that compensates for this effect as well as variations of equipment, personal handling, temperature and other laboratory conditions, must be determined directly after opening a new bottle and should be verified at regular intervals.
Global Trade Item Number
Catalogue Number GTIN
1.09164.1000 04022536111483
1.09164.1003 04054839999376