Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

805894 4-Methylmorpholine

4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H₂O, 20 °C).

4-Methylmorpholine MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: NMM, N-Methylmorpholine

CAS #: 109-02-4 EC Number: 203-640-0 Molar Mass: 101.15 g/mol Hill Formula: C₅H₁₁NO
View Products on Sigmaaldrich.com
805894
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
109-02-4203-640-0C₅H₁₁NO101.15 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8.05894.0005 Glass bottle 5 ml
8.05894.0250 Glass bottle 250 ml
8.05894.1000 Glass bottle 1 l
8.05894.2500 Glass bottle 2.5 l
Description
Catalogue Number805894
SynonymsNMM, N-Methylmorpholine
References
Product Information
CAS number109-02-4
EC number203-640-0
Hill FormulaC₅H₁₁NO
Molar Mass101.15 g/mol
HS Code2934 99 90
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Application4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H₂O, 20 °C).
Biological Information
Physicochemical Information
Boiling point112 - 114 °C
Density0.92 g/cm3 (20 °C)
Explosion limit2.2 - 11.8 %(V)
Flash point12 °C DIN 51755 Part 1
Ignition temperature165 °C DIN 51794
Melting Point-66 °C
pH value10.6 (50 g/l, H₂O, 20 °C)
Vapor pressure23.5 hPa (20 °C)
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 1960 mg/kg
LD 50 dermalLD50 Rabbit 1240 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal WordDanger
RTECSQE5775000
Storage class3 Flammable liquids
WGKWGK 1 slightly hazardous to water
Disposal1
Strongly contaminated halogen-free organic solvents: container A.
Safety Information
Categories of dangerhighly flammable, harmful, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2535 , 3 (8), II
Declaration (transport by air) IATA-DGRUN 2535 , 3 (8), II
Declaration (transport by sea) IMDG-CodeUN 2535 , 3 (8), II
Supplemental Information
Specifications
Color (visual)colorless
Appearance of substance (visual)clear
Assay (GC, area%)≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C)0.917 - 0.918
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8.05894.0005 04022536388083
8.05894.0250 04022536388090
8.05894.1000 04022536388106
8.05894.2500 04022536748092

Related Products & Applications

Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines