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820876 Nickel catalyst

(Produced according to a process of the type developed by Murray Raney, activated for hydrogenation) for synthesis

Nickel catalyst MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Nickel catalyst acc. Raney

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820876
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Overview

Replacement Information

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8208760100
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      		 Plastic bottle 100 g
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      8208760250
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      Limited Availability Limited Availability
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          		 Plastic bottle 250 g
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          Description
          Catalogue Number820876
          SynonymsNickel catalyst acc. Raney
          References
          Product Information
          HS Code3815 90 90
          Quality LevelMQ200
          Applications
          Biological Information
          Physicochemical Information
          Density>1.2 g/cm3
          pH value9 - 11 (H₂O, 20 °C) suspension
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H251: Self-heating: may catch fire.
          H317: May cause an allergic skin reaction.
          H351: Suspected of causing cancer.
          H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
          H412: Harmful to aquatic life with long lasting effects.
          Precautionary Statement(s)P202: Do not handle until all safety precautions have been read and understood.
          P235: Keep cool.
          P273: Avoid release to the environment.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P302 + P352: IF ON SKIN: Wash with plenty of water.
          P308 + P313: IF exposed or concerned: Get medical advice/ attention.
          P403 + P235: Store in a well-ventilated place. Keep cool.
          Signal WordDanger
          Storage class4.2 Pyrophoric and self-heating hazardous materials
          WGKWGK 2 obviously hazardous to water
          Disposal26
          Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
          Safety Information
          Categories of dangercarcinogenic, highly flammable, sensitizing, toxic, dangerous for the environment
          Product Usage Statements
          Storage and Shipping Information
          StorageStore below +30°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 1378 , 4.2, II
          Declaration (transport by air) IATA-DGRUN 1378 , 4.2, II
          Declaration (transport by sea) IMDG-CodeUN 1378 , 4.2, II
          Supplemental Information
          Specifications
          Assay of Ni, calc. on dried substance≥ 90.0 %
          Assay od Al, calc. on dried substance≤ 10.0 %
          Suitable for hydrogenation catalystpasses test
          Global Trade Item Number
          Catalogue Number GTIN
          8208760100 04022536468372
          8208760250 04022536911946

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          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Catalysts > Catalysts, Heterogeneous
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents