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103115 1,4-Dioxane

Overview

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
123-91-1204-661-8C₄H₈O₂88.11 g/mol

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1031151000
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      Glass bottle 1 l
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      1031152500
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          Glass bottle 2.5 l
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          1031156025
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              Drum stainl. st. 25 l
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              1031159191
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                  Steel barrel 190 l
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                  Description
                  Catalogue Number103115
                  SynonymsGlycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
                  OverviewEMPLURA® is our low-cost alternative to high-purity qualities. With EMPLURA® we offer a range of solvents for a plurality of basic applications in non-regulated industries and for less demanding applications, preparative laboratory work and cleaning purposes. EMPLURA® solvents provide adequate specifications with the most important parameters.
                  Product Information
                  CAS number123-91-1
                  EC index number603-024-00-5
                  EC number204-661-8
                  Hill FormulaC₄H₈O₂
                  Molar Mass88.11 g/mol
                  HS Code2932 99 00
                  Structure formula ImageStructure formula Image
                  Quality LevelMQ200
                  Physicochemical Information
                  Boiling point101.5 °C (1013 hPa)
                  Density1.034 g/cm3 (20 °C)
                  Explosion limit1.7 - 25.2 %(V)
                  Flash point11 °C
                  Ignition temperature300 °C
                  Melting Point11.8 °C
                  pH value6.0 - 8 (500 g/l, H₂O, 20 °C)
                  Vapor pressure36 hPa (20 °C)
                  Toxicological Information
                  LD 50 oralLD50 Rat 5200 mg/kg
                  LD 50 dermalLD50 Rabbit 7600 mg/kg
                  Safety Information according to GHS
                  Hazard Pictogram(s) Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Statement(s)H225: Highly flammable liquid and vapour.
                  H319: Causes serious eye irritation.
                  H335: May cause respiratory irritation.
                  H350: May cause cancer.
                  EUH019: May form explosive peroxides.
                  EUH066: Repeated exposure may cause skin dryness or cracking.
                  Precautionary Statement(s)P202: Do not handle until all safety precautions have been read and understood.
                  P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
                  P233: Keep container tightly closed.
                  P240: Ground and bond container and receiving equipment.
                  P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
                  P308 + P313: IF exposed or concerned: Get medical advice/ attention.
                  P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
                  Signal WordDanger
                  RTECSJG8225000
                  Storage class3 Flammable liquids
                  WGKWGK 3 highly hazardous to water
                  Disposal3
                  Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
                  Safety Information
                  Categories of dangerhighly flammable, irritant, carcinogenic
                  Storage and Shipping Information
                  StorageStore at +2°C to +30°C.
                  Transport Information
                  Declaration (railroad and road) ADR, RIDUN 1165 , 3, II
                  Declaration (transport by air) IATA-DGRUN 1165 , 3, II
                  Declaration (transport by sea) IMDG-CodeUN 1165 , 3, II
                  Specifications
                  Purity (GC)≥ 99.0 %
                  Identity (IR)conforms
                  Free acid (as CH₃COOH)≤ 0.01 %
                  Density (d 20 °C/ 4 °C)1.032 - 1.034
                  Peroxide (as H₂O₂)≤ 0.005 %
                  Water≤ 0.1 %
                  Stabilized with about 25 ppm 2,6-Di-tert-butyl-4-methylphenol (BHT)
                  Global Trade Item Number
                  Catalogue Number GTIN
                  1031151000 04022536040042
                  1031152500 04022536040066
                  1031156025 04022536040080
                  1031159191 04027269047740