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814109 Tributyltin hydride (stabilized)

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
688-73-3211-704-4C₁₂H₂₈Sn291.05 g/mol

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      8.14109.0100
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          Description
          Catalogue Number814109
          SynonymsTributylstannane
          References
          Product Information
          CAS number688-73-3
          EC index number050-008-00-3
          EC number211-704-4
          Hill FormulaC₁₂H₂₈Sn
          Molar Mass291.05 g/mol
          HS Code2931 20 00
          Structure formula ImageStructure formula Image
          Quality LevelMQ200
          Applications
          ApplicationTributyltin hydride for synthesis. CAS 688-73-3, molar mass 291.06 g/mol.
          Biological Information
          Physicochemical Information
          Boiling point112 - 114 °C (11 hPa)
          Density1.08 - 1.10 g/cm3 (20 °C)
          Flash point40 °C
          Ignition temperature>250 °C
          Vapor pressure5 hPa (20 °C)
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H226: Flammable liquid and vapour.
          H301: Toxic if swallowed.
          H312: Harmful in contact with skin.
          H315: Causes skin irritation.
          H319: Causes serious eye irritation.
          H360FD: May damage fertility. May damage the unborn child.
          H372: Causes damage to organs through prolonged or repeated exposure.
          H410: Very toxic to aquatic life with long lasting effects.
          Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
          P273: Avoid release to the environment.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
          P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          Signal WordDanger
          RTECSWH8675000
          Storage class3 Flammable liquids
          WGKWGK 3 highly hazardous to water
          Disposal26
          Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
          Safety Information
          Categories of dangertoxic, irritant, dangerous for the environment
          Product Usage Statements
          Storage and Shipping Information
          StorageStore below +30°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 2788 , 6.1, III
          Declaration (transport by air) IATA-DGRUN 2788 , 6.1, III
          Declaration (transport by sea) IMDG-CodeUN 2788 , 6.1, III, Marine Pollutant: P
          Supplemental Information
          Specifications
          Assay (GC, area%)≥ 97.0 % (a/a)
          Density (d 20 °C/ 4 °C)1.096 - 1.102
          Identity (IR)passes test
          The material is stabilised with Butylhydroxytoluene (BHT).
          At time of analytical testing a content of >300 ppm stabiliser was determined.
          Global Trade Item Number
          Catalogue Number GTIN
          8.14109.0025 04022536407012
          8.14109.0100 04022536407029

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          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Organometal Compounds