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109114 Potassium hydroxide solution in ethanol

109114
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

Grade Value
Reag. Ph Eur

Products

Catalogue NumberPackaging Qty/Pack
1091141000 Glass bottle 1 l
1091141003 Glass bottle 1 l
Description
Catalogue Number109114
References
Product Information
GradeReag. Ph Eur
HS Code3822 90 00
Quality LevelMQ200
Applications
ApplicationPotassium hydroxide solution in ethanol c(KOH) = 0.5 mol/l (0.5 N) Titripur® Reag. Ph Eur,Reag. USP. ph value 14 (H₂O, 20 °C).
Biological Information
Physicochemical Information
Boiling point78.3 °C (1013 hPa) (ethanol)
Density0.85 g/cm3 (20 °C)
Explosion limit3.5 - 15.0 %(V) (ethanol)
Flash point12 °C (ethanol)
Ignition temperature425 °C (ethanol)
Melting Point-114.5 °C (ethanol)
pH value14 (H₂O, 20 °C)
Vapor pressure59 hPa (20 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P234: Keep only in original packaging.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal WordDanger
Storage class3 Flammable liquids
WGKWGK 1 slightly hazardous to water
Disposal1
Strongly contaminated halogen-free organic solvents: container A.
Safety Information
Categories of dangerhighly flammable, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore at +15°C to +25°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2924 , 3 (8), II
Declaration (transport by air) IATA-DGRUN 2924 , 3 (8), II
Declaration (transport by sea) IMDG-CodeUN 2924 , 3 (8), II, Segregation Group: 18 (Alkalis)
Supplemental Information
Specifications
Formliquid
Amount-of-substance concentration0.4975 - 0.5025 mol/l
Measurement uncertainty+/- 0.0015
TraceabilityNIST SRM
The stated batch and specification values for the amount of substance concentration are valid at the time of bottling.
The amount-of-substance concentration of this volumetric solution is analyzed by our quality control laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025.
The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 350 benzoic acid) by means of volumetric standard benzoic acid (article number 1.02401), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.
Note: The concentration of this volumetric solution decreases over time, due to its chemical properties. If high accuracy is expected, the titer, being a corrective factor that compensates for this effect as well as variations of equipment, personal handling, temperature and other laboratory conditions, must be determined directly after opening a new bottle and should be verified at regular intervals.
Global Trade Item Number
Catalogue Number GTIN
1091141000 04022536110745
1091141003 04054839533679

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Reagents, Chemicals and Labware > Inorganic Reagents > Instrumental Inorganic Analysis > Volumetric Solutions Titripur®, Titripac®, Titrisol®, Titriplex® > Titripur® Ready-to-use Solutions