Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

841077 Boron hydride-tetrahydrofuran complex

(stabilised) (1 molar solution in tetrahydrofuran) for synthesis

Boron hydride-tetrahydrofuran complex MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
841077
Purchase on Sigma-Aldrich

Overview

Replacement Information

Products

Catalogue NumberPackaging Qty/Pack
8410770100 Glass bottle 100 ml
Description
Catalogue Number841077
References
Product Information
HS Code3824 99 92
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Biological Information
Physicochemical Information
Boiling point66 °C (1013 hPa) (THF)
Density0.876 g/cm3 (25 °C)
Explosion limit1.58 - 12.42 %(V)
Flash point-21.7 °C
Ignition temperature103 °C
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat > 500 - 2000 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H260: In contact with water releases flammable gases which may ignite spontaneously.
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer.
EUH014: Reacts violently with water.
EUH019: May form explosive peroxides.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P231 + P232: Handle and store contents under inert gas. Protect from moisture.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal WordDanger
Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 2 obviously hazardous to water
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Categories of dangerhighly flammable, irritant, carcinogenic, harmful
Product Usage Statements
Storage and Shipping Information
StorageStore at <= 20°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 3399 , 4.3 (3), I
Declaration (transport by air) IATA-DGRUN 3399 , 4.3 (3), I
Declaration (transport by sea) IMDG-CodeUN 3399 , 4.3 (3), I
Supplemental Information
Specifications
Assay (iodometric)0.8 - 1.2 mol/l
This product contains up to 0,005M sodium borohydride as a stabilizer.
Global Trade Item Number
Catalogue Number GTIN
8410770100 04022536627212

Documentation

Boron hydride-tetrahydrofuran complex SDS

Title

Safety Data Sheet (SDS) 

Boron hydride-tetrahydrofuran complex Certificates of Analysis

Product Number PackagingSpecificationLot Number
8410770100 Glass bottlePDF Specification Document

Related Products & Applications

Categories

Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Heterocycles > Heterocycles with 5-membered Rings > Di- and Tetrahydrofurans, Butyrolactones
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Heterocycles > Heterocycles with 5-membered Rings > Di- and Tetrahydrofurans, Butyrolactones
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Boric Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Heterocycles > Heterocycles with 5-membered Rings > Di- and Tetrahydrofurans, Butyrolactones
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Boric Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Boric Compounds