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822339 Phosphoryl chloride

822339
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
10025-87-3233-046-7Cl₃OPPOCl₃153.33 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8223390250 Glass btl. pl.coat. 250 ml
8223391000 Glass btl. pl.coat. 1 l
Description
Catalogue Number822339
SynonymsPhosphorus oxide trichloride, Phosphorus oxychloride
DescriptionPhosphoryl chloride
References
Product Information
CAS number10025-87-3
EC index number015-009-00-5
EC number233-046-7
Hill FormulaCl₃OP
Chemical formulaPOCl₃
Molar Mass153.33 g/mol
HS Code2812 12 00
Quality LevelMQ200
Applications
ApplicationPhosphoryl chloride for synthesis. CAS 10025-87-3, EC Number 233-046-7, chemical formula POCl₃.
Biological Information
Physicochemical Information
Boiling point105.3 °C (1013 hPa)
Density1.645 g/cm3 (25 °C) DIN 51757
Melting Point1.18 °C
pH value1 (H₂O, 20 °C)
Vapor pressure37 hPa (20 °C)
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 36 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H330: Fatal if inhaled.
H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
EUH014: Reacts violently with water.
EUH029: Contact with water liberates toxic gas.
Precautionary Statement(s)P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get medical advice/ attention if you feel unwell.
Signal WordDanger
RTECSTH4897000
Storage class6.1B Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 1 slightly hazardous to water
Disposal24
Liquid inorganic halides and hydrolysis-sensitive reagents can be carefully stirred dropwise into ice-cool 10% sodium hydroxide solution (Cat. No. 105587) (caution: caustic gases!); container D or E.
Safety Information
Categories of dangervery toxic, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1810 , 6.1 (8), I
Declaration (transport by air) IATA-DGRUN 1810 , 6.1 (8),
Declaration (transport by sea) IMDG-CodeUN 1810 , 6.1 (8), I, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Color according to color reference solution Ph.Eur.colorless liquid
Assay (argentometric)≥ 99.0 %
Density (d 20 °C/ 4 °C)1.673 - 1.677
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8223390250 04022536489759
8223391000 04022536489766

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Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Nucleotide Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Nucleotide Synthesis