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820502 Cumene hydroperoxide

(80% solution in cumene) for synthesis

Cumene hydroperoxide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: a,a-Dimethylbenzyl hydroperoxide, α,α-Dimethylbenzyl hydroperoxide

820502
Purchase on Sigma-Aldrich

Overview

Replacement Information

Products

Catalogue NumberPackaging Qty/Pack
8205020005 Glass bottle 5 ml
8205020250 Glass bottle 250 ml
Description
Catalogue Number820502
Synonymsa,a-Dimethylbenzyl hydroperoxide, α,α-Dimethylbenzyl hydroperoxide
References
Product Information
HS Code2909 60 19
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Biological Information
Physicochemical Information
Boiling point116 °C (20 hPa)
Density1.03 g/cm3 (20 °C)
Flash point57 °C
Melting Point<-30 °C
pH value>5 (13 g/l, H₂O, 20 °C)
Solubility13 g/l
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 573 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H226: Flammable liquid and vapour.
H242: Heating may cause a fire.
H302 + H312: Harmful if swallowed or in contact with skin.
H304: May be fatal if swallowed and enters airways.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.
H335: May cause respiratory irritation.
H350: May cause cancer.
H373: May cause damage to organs through prolonged or repeated exposure if inhaled.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
Signal WordDanger
Storage class5.2 Organic peroxides and self-reacting hazardous materials
WGKWGK 3 highly hazardous to water
Disposal10
Organic peroxides can be detected in aqueous solutions or organic solvents using the Perex-Test® (Cat. No. 116206). Pure peroxides are diluted to min. 10% in a suitable solvent or with water and added in small portions, with temperature control, to iron(II) chloride (Cat. No. 103860) solution. Test for complete reaction with the Perex-Test® (Cat. No. 116206). Container D. Explosive substances (storage class 4.1A) should be packed separately and tightly sealed for disposal. Ensure sufficient phlegmatization by water or the stated phlegmatizing agent!
Safety Information
Product Usage Statements
Storage and Shipping Information
StorageStore at +15°C to +25°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 3109 , 5.2 (8),
Declaration (transport by air) IATA-DGRUN 3109 , 5.2 (8),
Declaration (transport by sea) IMDG-CodeUN 3109 , 5.2 (8),
Supplemental Information
Specifications
Assay (iodometric)82.0 - 87.0 %
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8205020005 04022536460291
8205020250 04022536460314

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Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Oxidation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Carboxylic Acid Derivatives > Other Carboxylic Acid Derivatives > Peracids and Peroxides