Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

102444 Chloroform

Chloroform for liquid chromatography LiChrosolv®. CAS 67-66-3, molar mass 119.38 g/mol.

Chloroform MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Trichloromethane, TCM, Methane trichloride, Methyl trichloride

CAS #: 67-66-3 EC Number: 200-663-8 Molar Mass: 119.38 g/mol Hill Formula: CHCl₃
102444
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
67-66-3200-663-8CHCl₃119.38 g/mol

Products

Catalogue NumberPackaging Qty/Pack
1024441000 Glass bottle 1 l
1024442500 Glass bottle 2.5 l
1024444000 Glass bottle 4 l
Description
Catalogue Number102444
SynonymsTrichloromethane, TCM, Methane trichloride, Methyl trichloride
OverviewWith their high degree of UV transmittance, low particle count, low acidity and alkalinity and low evaporation residue level, LiChrosolv® solvents are ideal for reproducible separations. Since separations are normally carried out under gradient conditions in analytical HPLC, we offer solvents in "gradient grade" as well as "isocratic grade". This enables to minimize the gradient effect of the solvent involved.
References
Product Information
CAS number67-66-3
EC index number602-006-00-4
EC number200-663-8
Hill FormulaCHCl₃
Molar Mass119.38 g/mol
HS Code2903 13 00
Structure formula ImageStructure formula Image
Quality LevelMQ100
Applications
ApplicationChloroform for liquid chromatography LiChrosolv®. CAS 67-66-3, molar mass 119.38 g/mol.
Biological Information
Physicochemical Information
Boiling point61 °C (1013 hPa)
Density1.49 g/cm3 (25 °C)
Melting Point-64 °C
Vapor pressure210 hPa (20 °C)
Solubility8 g/l
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 695 mg/kg
LD 50 dermalLD50 Rabbit > 3980 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer.
H361d: Suspected of damaging the unborn child.
H372: Causes damage to organs through prolonged or repeated exposure if swallowed.
Precautionary Statement(s)P202: Do not handle until all safety precautions have been read and understood.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
Signal WordDanger
RTECSFS9100000
Storage class6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3 highly hazardous to water
Disposal3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety Information
Categories of dangerharmful, irritant, carcinogenic, toxic for reproduction
Product Usage Statements
Storage and Shipping Information
StorageStore at +2°C to +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1888 , 6.1, III
Declaration (transport by air) IATA-DGRUN 1888 , 6.1, III
Declaration (transport by sea) IMDG-CodeUN 1888 , 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)
Supplemental Information
Specifications
Purity (GC)≥ 99.8 %
Identity (IR)conforms
Evaporation residue≤ 5.0 mg/l
Water≤ 0.01 %
Acidity≤ 0.0002 meq/g
Alkalinity≤ 0.0002 meq/g
Transmission (at 255 nm)≥ 70 %
Transmission (at 260 nm)≥ 85 %
Transmission (from 300 nm)≥ 98 %
Stabilized with 2-methyl-2-butene and methanol.
For additional instructions see actual safety data sheet (SDS) chapter 7.
The purpose is only for high pressure liquid chromatography.
Filtered by 0.2 µm filter.
Global Trade Item Number
Catalogue Number GTIN
1024441000 04022536033532
1024442500 04022536033556
1024444000 04022536658209

Related Products & Applications

Accessories (Primary)

Catalogue Number Description
109996 Adapter S 40
963533 Safety carrier

Accessories (Secondary)

Catalogue Number Description
100801 Label set acc. GHS
103830 HPLC-bottle adapter with 3 tube connections ID 3.2 mm, solvents supply
103831 HPLC bottle adapter S40 with 3 tube connections and 1 connection for exhaust air filter, solvents disposal
103833 Exhaust air filter for HPLC bottle adapter S40, disposal
108801 Bottle key

Related Products By: Application Facete

LC Liquid Chromatography
Gradient Elution
HPLC High Performance Liquid Chromatography
Isocratic HPLC

Related Products By: Brand Facete

LiChrosolv®

Categories

Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Liquid Chromatography, LiChrosolv®
Analytics and Sample Preparation > Analytical Chromatography > Mobile Phases for Chromatography > Solvents for Liquid Chromatography, LiChrosolv®