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802100 Calcium hydride

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
7789-78-8232-189-2H₂CaCaH₂42.1 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8021000100 Glass bottle 100 g
8021000500 Glass bottle 500 g
Description
Catalogue Number802100
DescriptionCalcium hydride
References
Product Information
CAS number7789-78-8
EC index number001-004-00-5
EC number232-189-2
Hill FormulaH₂Ca
Chemical formulaCaH₂
Molar Mass42.1 g/mol
HS Code2850 00 90
Quality LevelMQ200
Applications
ApplicationCalcium hydride for synthesis. CAS 7789-78-8, chemical formula CaH₂.
Biological Information
Physicochemical Information
Density1.900 g/cm3
Ignition temperature>300 °C
Melting Point816 °C
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
Precautionary Statement(s)P223: Do not allow contact with water.
P231 + P232: Handle and store contents under inert gas. Protect from moisture.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.
P501: Dispose of contents/ container to an approved waste disposal plant.
Signal WordDanger
Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 1 slightly hazardous to water
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Categories of dangerhighly flammable
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1404 , 4.3, I
Declaration (transport by air) IATA-DGRUN 1404 , 4.3, I
Declaration (transport by sea) IMDG-CodeUN 1404 , 4.3, I
Supplemental Information
Specifications
Assay (by gasvolumetry)≥ 95.0 %
Global Trade Item Number
Catalogue Number GTIN
8021000100 04022536371818
8021000500 04022536371825

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Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Hydrides and Amides
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents