Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

843705 Sodium triacetoxyborohydride

843705
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #Hill FormulaMolar Mass
56553-60-7C₆H₁₀BNaO₈211.94 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8437050025 Glass bottle 25 g
8437050100 Glass bottle 100 g
8437059999 0
Description
Catalogue Number843705
References
Product Information
CAS number56553-60-7
Hill FormulaC₆H₁₀BNaO₈
Molar Mass211.94 g/mol
HS Code2942 00 00
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
ApplicationSodium triacetoxyborohydride for synthesis. CAS 56553-60-7, molar mass 211.94 g/mol.
Biological Information
Physicochemical Information
Density1.36 g/cm3 (20.1 °C)
Melting Point111 - 111.2 °C
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H228: Flammable solid.
H260: In contact with water releases flammable gases which may ignite spontaneously.
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H360FD: May damage fertility. May damage the unborn child.
EUH014: Reacts violently with water.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P231 + P232: Handle and store contents under inert gas. Protect from moisture.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P402 + P404: Store in a dry place. Store in a closed container.
Signal WordDanger
Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 2 obviously hazardous to water
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Categories of dangerhighly flammable, irritant
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 3396 , 4.3 (4.1), II
Declaration (transport by air) IATA-DGRUN 3396 , 4.3 (4.1), II
Declaration (transport by sea) IMDG-CodeUN 3396 , 4.3 (4.1), II
Supplemental Information
Specifications
Assay (acidimetric)≥ 96.0 %
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8437050025 04027269059460
8437050100 04027269059477
8437059999 04027269059484