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102447 Chloroform

102447
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
67-66-3200-663-8CHCl₃CHCl₃119.38 g/mol

Products

Catalogue NumberPackaging Qty/Pack
1024470500 Glass bottle 500 ml
1024472500 Glass bottle 2.5 l
Description
Catalogue Number102447
SynonymsTCM, Trichloromethane, Methane trichloride, Methyl trichloride
DescriptionChloroform
OverviewAccurate analytic results in UV/VIS and infrared spectroscopy depend on the use of very pure solvents for sample preparation. The Uvasol® solvents range has been specially designed for spectroscopy and other applications requiring solvents of the highest spectral purity. The refinement process allows a greater degree of security in applications and avoids misinterpretation of analytical results caused by traces of UV, IR and fluorescence contamination. Uvasol® solvents offer best UV transmittance. In all specifications the minimum transmittance for 5 typical wavelengths are identified.
References
Product Information
CAS number67-66-3
EC index number602-006-00-4
EC number200-663-8
Hill FormulaCHCl₃
Chemical formulaCHCl₃
Molar Mass119.38 g/mol
HS Code2903 13 00
Structure formula ImageStructure formula Image
Quality LevelMQ100
Applications
ApplicationChloroform for spectroscopy Uvasol®. CAS 67-66-3, chemical formula CHCl₃.
Biological Information
Physicochemical Information
Boiling point61 °C (1013 hPa)
Density1.49 g/cm3 (25 °C)
Melting Point-64 °C
Vapor pressure210 hPa (20 °C)
Solubility8.7 g/l
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 695 mg/kg
LD 50 dermalLD50 Rabbit > 3980 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer.
H361d: Suspected of damaging the unborn child.
H372: Causes damage to organs through prolonged or repeated exposure if swallowed.
Precautionary Statement(s)P202: Do not handle until all safety precautions have been read and understood.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
Signal WordDanger
RTECSFS9100000
Storage class6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3 highly hazardous to water
Disposal2
Organic halogenated solvents and solutions of organic halogen-containing substances: For strongly contaminated or mixed halogenated solvents container B: Caution: Do not use aluminium containers; in addition, in the case of water-containing chlorinated waste materials do not use stainless-steel containers (danger of leaks caused by corrosion).
Safety Information
Categories of dangerharmful, irritant, carcinogenic, toxic for reproduction
Product Usage Statements
Storage and Shipping Information
StorageStore at +2°C to +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1888 , 6.1, III
Declaration (transport by air) IATA-DGRUN 1888 , 6.1, III
Declaration (transport by sea) IMDG-CodeUN 1888 , 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)
Supplemental Information
Specifications
Purity (GC)≥ 99.0 %
Evaporation residue≤ 0.0002 %
Water≤ 0.01 %
Color≤ 10 Hazen
Acidity≤ 0.0002 meq/g
Alkalinity≤ 0.0002 meq/g
Fluorescence (as quinine at 254 nm)≤ 1.0 ppb
Fluorescence (as quinine at 365 nm)≤ 1.0 ppb
Transmission (at 245 nm)≥ 15 %
Transmission (at 250 nm)≥ 50 %
Transmission (at 255 nm)≥ 60 %
Transmission (at 260 nm)≥ 85 %
Transmission (from 270 nm)≥ 98 %
Absorbance (at 245 nm)≤ 0.82
Absorbance (at 250 nm)≤ 0.30
Absorbance (at 255 nm)≤ 0.22
Absorbance (at 260 nm)≤ 0.07
Absorbance (from 270 nm)≤ 0.01
The product is stabilized with about 1% ethanol.
Meet the requirements of "Specific use spectroscopy" according ACS
Global Trade Item Number
Catalogue Number GTIN
1024470500 04022536033716
1024472500 04022536033730

Related Products & Applications

Accessories (Primary)

Catalogue Number Description
963533 Safety carrier

Accessories (Secondary)

Catalogue Number Description
100801 Label set acc. GHS
108801 Bottle key

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Categories

Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Spectroscopy, Uvasol®
Analytics and Sample Preparation > Spectroscopy > Solvents for Spectroscopy, Uvasol®
Analytics and Sample Preparation > Spectroscopy > UV/VIS Spectroscopy > Solvents for UV/VIS Spectroscopy