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818043 Trifluoromethanesulfonic anhydride

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
358-23-6206-616-8C₂F₆O₅S₂(CF₃SO₂)₂O282.13 g/mol

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8180430002
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      8180430050
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          Description
          Catalogue Number818043
          DescriptionTrifluoromethanesulfonic anhydride
          References
          Product Information
          CAS number358-23-6
          EC number206-616-8
          Hill FormulaC₂F₆O₅S₂
          Chemical formula(CF₃SO₂)₂O
          Molar Mass282.13 g/mol
          HS Code2904 99 00
          Structure formula ImageStructure formula Image
          Quality LevelMQ200
          Applications
          ApplicationTrifluoromethanesulfonic anhydride for synthesis. CAS 358-23-6, EC Number 206-616-8, chemical formula (CF₃SO₂)₂O.
          Biological Information
          Physicochemical Information
          Density1.716 g/cm3 (20 °C)
          Melting Point-82 °C
          Vapor pressure10 hPa (20 °C)
          Dimensions
          Materials Information
          Toxicological Information
          LD 50 oralLD50 Rat 1012 mg/kg
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H272: May intensify fire; oxidizer.
          H302: Harmful if swallowed.
          H314: Causes severe skin burns and eye damage.
          H335: May cause respiratory irritation.
          EUH014: Reacts violently with water.
          Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
          P220: Keep away from clothing and other combustible materials.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
          P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          Signal WordDanger
          Storage class5.1B Oxidizing hazardous materials
          WGKWGK 3 highly hazardous to water
          Disposal12
          Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.
          Safety Information
          Categories of dangerharmful, corrosive
          Product Usage Statements
          Storage and Shipping Information
          StorageStore below +30°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 3098 , 5.1 (8), II
          Declaration (transport by air) IATA-DGRUN 3098 , 5.1 (8), II
          Declaration (transport by sea) IMDG-CodeUN 3098 , 5.1 (8), II
          Supplemental Information
          Specifications
          Assay (acidimetric)≥ 99.0 %
          Density (d 20 °C/ 4 °C)1.715 - 1.720
          Identity (IR)passes test
          Global Trade Item Number
          Catalogue Number GTIN
          8180430002 04027269276003
          8180430050 04027269123857

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          Categories

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          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Sulfur Compounds > Sulfonic Acids and Derivatives > Sulfonic Acid Chlorides and Anhydrides
          Reagents, Chemicals and Labware > Organic Synthesis > XXS Products in Small Quantities
          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Sulfur Compounds > Sulfonic Acids and Derivatives > Sulfonic Acid Chlorides and Anhydrides