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814109 Tributyltin hydride (stabilized)

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
688-73-3211-704-4C₁₂H₂₈Sn291.05 g/mol

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8141090005
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      8141090025
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          8141090100
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              Description
              Catalogue Number814109
              SynonymsTributylstannane
              References
              Product Information
              CAS number688-73-3
              EC index number050-008-00-3
              EC number211-704-4
              Hill FormulaC₁₂H₂₈Sn
              Molar Mass291.05 g/mol
              HS Code2931 20 00
              Structure formula ImageStructure formula Image
              Quality LevelMQ200
              Applications
              ApplicationTributyltin hydride for synthesis. CAS 688-73-3, molar mass 291.06 g/mol.
              Biological Information
              Physicochemical Information
              Boiling point112 - 114 °C (11 hPa)
              Density1.08 - 1.10 g/cm3 (20 °C)
              Flash point40 °C
              Ignition temperature>250 °C
              Vapor pressure5 hPa (20 °C)
              Dimensions
              Materials Information
              Toxicological Information
              Safety Information according to GHS
              Hazard Pictogram(s) Hazard Pictogram(s)
              Hazard Pictogram(s)
              Hazard Pictogram(s)
              Hazard Pictogram(s)
              Hazard Statement(s)H226: Flammable liquid and vapour.
              H301: Toxic if swallowed.
              H312: Harmful in contact with skin.
              H315: Causes skin irritation.
              H319: Causes serious eye irritation.
              H360FD: May damage fertility. May damage the unborn child.
              H372: Causes damage to organs through prolonged or repeated exposure.
              H410: Very toxic to aquatic life with long lasting effects.
              Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
              P273: Avoid release to the environment.
              P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
              P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
              P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
              P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
              Signal WordDanger
              RTECSWH8675000
              Storage class3 Flammable liquids
              WGKWGK 3 highly hazardous to water
              Disposal26
              Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
              Safety Information
              Categories of dangertoxic, irritant, dangerous for the environment
              Product Usage Statements
              Storage and Shipping Information
              StorageStore below +30°C.
              Packaging Information
              Transport Information
              Declaration (railroad and road) ADR, RIDUN 2788 , 6.1, III
              Declaration (transport by air) IATA-DGRUN 2788 , 6.1, III
              Declaration (transport by sea) IMDG-CodeUN 2788 , 6.1, III, Marine Pollutant: P
              Supplemental Information
              Specifications
              Assay (GC, area%)≥ 97.0 % (a/a)
              Density (d 20 °C/ 4 °C)1.096 - 1.102
              Identity (IR)passes test
              The material is stabilised with Butylhydroxytoluene (BHT).
              At time of analytical testing a content of >300 ppm stabiliser was determined.
              Global Trade Item Number
              Catalogue Number GTIN
              8141090005 04027269276294
              8141090025 04022536407012
              8141090100 04022536407029

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              Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
              Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
              Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
              Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents
              Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Organometal Compounds