8.18287
Lithium iodide
anhydrous for synthesis
동의어(들):
Lithium iodide
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
ILi
CAS 번호:
Molecular Weight:
133.85
UNSPSC Code:
12352302
EC Index Number:
233-822-5
NACRES:
NA.22
MDL number:
Grade:
synthesis grade
Form:
powder
Solubility:
soluble 1640 g/L
제품 이름
Lithium iodide, anhydrous for synthesis
SMILES string
[Li+].[I-]
InChI
1S/HI.Li/h1H;/q;+1/p-1
InChI key
HSZCZNFXUDYRKD-UHFFFAOYSA-M
grade
synthesis grade
form
powder
greener alternative product characteristics
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mp
450 °C
solubility
soluble 1640 g/L
density
4 g/cm3 at 20 °C
bulk density
1000 kg/m3
greener alternative category
storage temp.
2-30°C
Quality Level
관련 카테고리
Analysis Note
Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 0.50 %
Water (K. F.): ≤ 0.50 %
Application
Lithium iodide (LiI) can be used as a catalyst to synthesize:
It can also be used as:
- N-alkyl 2-pyridone derivatives via O- to N-[1,3]-alkyl migration.
- β-mannosides and β-rhamnosides from glycosyl hemiacetals via one-pot chlorination, iodination, and glycosylation reaction.
It can also be used as:
- Solid electrolyte in the synthesis of Vycor glass/LiI composites applicable in the development of solid-state batteries.
- Iodine source to synthesize primary, secondary, and bridgehead tertiary alkyl iodides by PPh3-catalyzed iododecarboxylation of aliphatic carboxylates.
General description
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저장 등급
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
Imlirenla Pongener et al.
Chemical science, 12(29), 10070-10075 (2021-08-12)
Stereoselective β-mannosylation is one of the most challenging problems in the synthesis of oligosaccharides. Herein, a highly selective synthesis of β-mannosides and β-rhamnosides from glycosyl hemi-acetals is reported, following a one-pot chlorination, iodination, glycosylation sequence employing cheap oxalyl chloride, phosphine
Triphenylphosphine-Catalyzed Alkylative Iododecarboxylation with Lithium Iodide under Visible Light.
Ming-Chen Fu et al.
Organic letters, 22(21), 8572-8577 (2020-10-23)
Under irradiation of 456 nm blue light-emitting diodes, PPh3 catalyzes the iododecarboxylation of aliphatic carboxylic acid derived N-(acyloxy)phthalimide with lithium iodide as an iodine source. The reaction delivers primary, secondary, and bridgehead tertiary alkyl iodides in acetone solvent, and the
Preparation of N-alkyl 2-pyridones via a lithium iodide promoted O- to N-alkyl migration: scope and mechanism
Sarah Z Tasker, et al.
The Journal of Organic Chemistry, 77(18), 8220-8230 (2012)
Nanostructured ionic conductors: A study of Vycor7930-LiI composites
Albert Stephanie, et al.
Materials Science and Engineering Technology, 150(3), 199-202 (2008)
Sarah Z Tasker et al.
The Journal of organic chemistry, 77(18), 8220-8230 (2012-08-30)
An efficient and inexpensive LiI-promoted O- to N-alkyl migration of 2-benzyloxy-, 2-allyloxy-, and 2-propargyloxypyridines and heterocycles is reported. The reaction produces the corresponding N-alkyl 2-pyridones and analogues under green, solvent-free conditions in good to excellent yields (30 examples, 20-97% yield).
국제 무역 품목 번호
| SKU | GTIN |
|---|---|
| 8.18287.0002 | 04027269276614 |
| 8.18287.0050 | 04022536432328 |
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