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802100 Calcium hydride

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
7789-78-8232-189-2H₂CaCaH₂42.1 g/mol

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      Glass bottle 100 g
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      8.02100.0500
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          Description
          Catalogue Number802100
          DescriptionCalcium hydride
          References
          Product Information
          CAS number7789-78-8
          EC index number001-004-00-5
          EC number232-189-2
          Hill FormulaH₂Ca
          Chemical formulaCaH₂
          Molar Mass42.1 g/mol
          HS Code2850 00 90
          Quality LevelMQ200
          Applications
          ApplicationCalcium hydride for synthesis. CAS 7789-78-8, chemical formula CaH₂.
          Biological Information
          Physicochemical Information
          Density1.900 g/cm3
          Ignition temperature>300 °C
          Melting Point816 °C
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
          H315: Causes skin irritation.
          H319: Causes serious eye irritation.
          Precautionary Statement(s)P223: Do not allow contact with water.
          P231 + P232: Handle and store contents under inert gas. Protect from moisture.
          P264: Wash skin thoroughly after handling.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P302 + P352: IF ON SKIN: Wash with plenty of water.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P402 + P404: Store in a dry place. Store in a closed container.
          P501: Dispose of contents/ container to an approved waste disposal plant.
          Signal WordDanger
          Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
          WGKWGK 1 slightly hazardous to water
          Disposal26
          Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
          Safety Information
          Categories of dangerhighly flammable
          Product Usage Statements
          Storage and Shipping Information
          StorageStore below +30°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 1404 , 4.3, I
          Declaration (transport by air) IATA-DGRUN 1404 , 4.3, I
          Declaration (transport by sea) IMDG-CodeUN 1404 , 4.3, I
          Supplemental Information
          Specifications
          Assay (by gasvolumetry)≥ 95.0 %
          Global Trade Item Number
          Catalogue Number GTIN
          8.02100.0100 04022536371818
          8.02100.0500 04022536371825

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          Categories

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          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents