Millipore Sigma Vibrant Logo

805894 4-Methylmorpholine

4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H₂O, 20 °C).

4-Methylmorpholine MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: NMM, N-Methylmorpholine

CAS #: 109-02-4 EC Number: 203-640-0 Molar Mass: 101.15 g/mol Hill Formula: C₅H₁₁NO
View Products on Sigmaaldrich.com
805894
View Pricing & Availability

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
109-02-4203-640-0C₅H₁₁NO101.15 g/mol

Pricing & Availability

Catalogue Number AvailabilityPackaging Qty/Pack Price Quantity
8.05894.0005
Retrieving availability...
—
Limited Availability Limited Availability
In Stock 
Discontinued
Limited Quantities Available
Availability to be confirmed
    Remaining : Will advise
      Remaining : Will advise
      Will advise
      Contact Customer Service
      Contact Customer Service

      		 Glass bottle 5 ml
      Retrieving price...
      Price could not be retrieved
      Minimum Quantity is a multiple of
      Maximum Quantity is
      Upon Order Completion More Information
      You Saved ()
       
      —
      Request Pricing
      		 —
      8.05894.0250
      Retrieving availability...
      —
      Limited Availability Limited Availability
      In Stock 
      Discontinued
      Limited Quantities Available
      Availability to be confirmed
        Remaining : Will advise
          Remaining : Will advise
          Will advise
          Contact Customer Service
          Contact Customer Service

          		 Glass bottle 250 ml
          Retrieving price...
          Price could not be retrieved
          Minimum Quantity is a multiple of
          Maximum Quantity is
          Upon Order Completion More Information
          You Saved ()
           
          —
          Request Pricing
          		 —
          8.05894.1000
          Retrieving availability...
          —
          Limited Availability Limited Availability
          In Stock 
          Discontinued
          Limited Quantities Available
          Availability to be confirmed
            Remaining : Will advise
              Remaining : Will advise
              Will advise
              Contact Customer Service
              Contact Customer Service

              		 Glass bottle 1 l
              Retrieving price...
              Price could not be retrieved
              Minimum Quantity is a multiple of
              Maximum Quantity is
              Upon Order Completion More Information
              You Saved ()
               
              —
              Request Pricing
              		 —
              8.05894.2500
              Retrieving availability...
              —
              Limited Availability Limited Availability
              In Stock 
              Discontinued
              Limited Quantities Available
              Availability to be confirmed
                Remaining : Will advise
                  Remaining : Will advise
                  Will advise
                  Contact Customer Service
                  Contact Customer Service

                  		 Glass bottle 2.5 l
                  Retrieving price...
                  Price could not be retrieved
                  Minimum Quantity is a multiple of
                  Maximum Quantity is
                  Upon Order Completion More Information
                  You Saved ()
                   
                  —
                  Request Pricing
                  		 —
                  8.05894.9025
                  Retrieving availability...
                  —
                  Limited Availability Limited Availability
                  In Stock 
                  Discontinued
                  Limited Quantities Available
                  Availability to be confirmed
                    Remaining : Will advise
                      Remaining : Will advise
                      Will advise
                      Contact Customer Service
                      Contact Customer Service

                      		 Barrel PE/met 25 kg
                      Retrieving price...
                      Price could not be retrieved
                      Minimum Quantity is a multiple of
                      Maximum Quantity is
                      Upon Order Completion More Information
                      You Saved ()
                       
                      —
                      Request Pricing
                      		 —
                      Description
                      Catalogue Number805894
                      SynonymsNMM, N-Methylmorpholine
                      References
                      Product Information
                      CAS number109-02-4
                      EC number203-640-0
                      Hill FormulaC₅H₁₁NO
                      Molar Mass101.15 g/mol
                      HS Code2934 99 90
                      Structure formula ImageStructure formula Image
                      Quality LevelMQ200
                      Applications
                      Application4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H₂O, 20 °C).
                      Biological Information
                      Physicochemical Information
                      Boiling point112 - 114 °C
                      Density0.92 g/cm3 (20 °C)
                      Explosion limit2.2 - 11.8 %(V)
                      Flash point12 °C DIN 51755 Part 1
                      Ignition temperature165 °C DIN 51794
                      Melting Point-66 °C
                      pH value10.6 (50 g/l, H₂O, 20 °C)
                      Vapor pressure23.5 hPa (20 °C)
                      Dimensions
                      Materials Information
                      Toxicological Information
                      LD 50 oralLD50 Rat 1960 mg/kg
                      LD 50 dermalLD50 Rabbit 1240 mg/kg
                      Safety Information according to GHS
                      Hazard Pictogram(s) Hazard Pictogram(s)
                      Hazard Pictogram(s)
                      Hazard Pictogram(s)
                      Hazard Statement(s)H225: Highly flammable liquid and vapour.
                      H302: Harmful if swallowed.
                      H314: Causes severe skin burns and eye damage.
                      Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
                      P233: Keep container tightly closed.
                      P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
                      P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
                      P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
                      P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
                      P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
                      Signal WordDanger
                      RTECSQE5775000
                      Storage class3 Flammable liquids
                      WGKWGK 1 slightly hazardous to water
                      Disposal1
                      Strongly contaminated halogen-free organic solvents: container A.
                      Safety Information
                      Categories of dangerhighly flammable, harmful, corrosive
                      Product Usage Statements
                      Storage and Shipping Information
                      StorageStore below +30°C.
                      Packaging Information
                      Transport Information
                      Declaration (railroad and road) ADR, RIDUN 2535 , 3 (8), II
                      Declaration (transport by air) IATA-DGRUN 2535 , 3 (8), II
                      Declaration (transport by sea) IMDG-CodeUN 2535 , 3 (8), II
                      Supplemental Information
                      Specifications
                      Color (visual)colorless
                      Appearance of substance (visual)clear
                      Assay (GC, area%)≥ 98.0 % (a/a)
                      Density (d 20 °C/ 4 °C)0.917 - 0.918
                      Identity (IR)passes test
                      Global Trade Item Number
                      Catalogue Number GTIN
                      8.05894.0005 04022536388083
                      8.05894.0250 04022536388090
                      8.05894.1000 04022536388106
                      8.05894.2500 04022536748092
                      8.05894.9025 04022536868257

                      Documentation

                      4-Methylmorpholine SDS

                      Title

                      Safety Data Sheet (SDS) 

                      4-Methylmorpholine Certificates of Analysis

                      Product Number PackagingSpecificationLot Number
                      8.05894.0005 Glass bottlePDF Specification Document
                      8.05894.0250 Glass bottlePDF Specification Document
                      8.05894.1000 Glass bottlePDF Specification Document
                      8.05894.2500 Glass bottlePDF Specification Document
                      8.05894.9025 Barrel PE/metPDF Specification Document

                      Related Products & Applications

                      Categories

                      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines
                      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines
                      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Heterocycles > Heterocycles with 6-membered Rings > 1,4-Oxazines, Morpholines