Millipore Sigma Vibrant Logo

814552 Sodium hydride suspension

Sodium hydride suspension (60% suspension in paraffin oil) for synthesis. CAS No. 7646-69-7, EC Number 231-587-3.

Sodium hydride suspension MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
CAS #: 7646-69-7 EC Number: 231-587-3 Molar Mass: 24.0 g/mol Chemical Formula: NaH Hill Formula: HNa
814552
View Pricing & Availability

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
7646-69-7231-587-3HNaNaH24.0 g/mol

Pricing & Availability

Catalogue Number AvailabilityPackaging Qty/Pack Price Quantity
8.14552.0100
Retrieving availability...
—
Limited Availability Limited Availability
In Stock 
Discontinued
Limited Quantities Available
Availability to be confirmed
    Remaining : Will advise
      Remaining : Will advise
      Will advise
      Contact Customer Service
      Contact Customer Service

      		 Glass bottle 100 g
      Retrieving price...
      Price could not be retrieved
      Minimum Quantity is a multiple of
      Maximum Quantity is
      Upon Order Completion More Information
      You Saved ()
       
      —
      Request Pricing
      		 —
      Description
      Catalogue Number814552
      References
      Product Information
      CAS number7646-69-7
      EC index number001-003-00-X
      EC number231-587-3
      Hill FormulaHNa
      Chemical formulaNaH
      Molar Mass24.0 g/mol
      HS Code3824 99 79
      Quality LevelMQ200
      Applications
      ApplicationSodium hydride suspension (60% suspension in paraffin oil) for synthesis. CAS No. 7646-69-7, EC Number 231-587-3.
      Biological Information
      Physicochemical Information
      Density0.92 g/cm3 (20 °C)
      Dimensions
      Materials Information
      Toxicological Information
      Safety Information according to GHS
      Hazard Pictogram(s) Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
      H290: May be corrosive to metals.
      H304: May be fatal if swallowed and enters airways.
      H314: Causes severe skin burns and eye damage.
      Precautionary Statement(s)P231 + P232: Handle and store contents under inert gas. Protect from moisture.
      P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
      P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
      P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
      P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
      P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
      P402 + P404: Store in a dry place. Store in a closed container.
      Signal WordDanger
      Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
      WGKWGK 2 obviously hazardous to water
      Disposal26
      Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
      Safety Information
      Categories of dangerhighly flammable, corrosive
      Product Usage Statements
      Storage and Shipping Information
      StorageStore below +30°C.
      Packaging Information
      Transport Information
      Declaration (railroad and road) ADR, RIDUN 1427 , 4.3, I
      Declaration (transport by air) IATA-DGRUN 1427 , 4.3, I
      Declaration (transport by sea) IMDG-CodeUN 1427 , 4.3, I
      Supplemental Information
      Specifications
      Assay (by gasvolumetry)≥ 57.0 %
      Global Trade Item Number
      Catalogue Number GTIN
      8.14552.0100 04022536417110

      Related Products & Applications

      Categories

      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Organometallic Synthesis
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Hydrides and Amides
      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Organometallic Synthesis
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents