8.03646
Diisopropylamine
for synthesis
Synonym(s):
Diisopropylamine, N,N-Diisopropylamine, Bis(1-methylethyl)amine
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About This Item
grade
synthesis grade
Quality Segment
vapor pressure
93.33 hPa ( 20 °C)
assay
≥99% (GC)
form
liquid
autoignition temp.
295 °C
potency
420 mg/kg LD50, oral (Rat), 2900 mg/kg LD50, skin (Rabbit)
expl. lim.
1.1-7.1 % (v/v)
dilution
(for synthesis)
pH
11.8 (20 °C, 6 g/L in H2O)
bp
83-84 °C/1013 hPa
mp
-70 °C
transition temp
flash point -13.45 °C (DIN 51755 Part 1)
density
0.72 g/cm3 at 20 °C
storage temp.
2-30°C
SMILES string
N(C(C)C)C(C)C
InChI
1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3
InChI key
UAOMVDZJSHZZME-UHFFFAOYSA-N
General description
Application
- A reagent to synthesize furan, dihydrofuran, or butanolide derivatives by reacting with γ-ketothioesters.
- A catalyst to prepare aryl disulfides via oxidative coupling of aryl thiols in the presence of air as an oxidant.
- A base in Pd-catalyzed cross-coupling reactions such as Heck and Sonogashira reaction.
It can also be used as a starting material to prepare lithium diisopropylamide (LDA), a strong non-nucleophilic base widely used in organic synthesis for deprotonation reactions.
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signalword
Danger
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
flash_point_f
7.8 °F - closed cup
flash_point_c
-13.45 °C - closed cup
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - PMT - Repr. 1B - Skin Corr. 1B - STOT SE 3 - vPvM
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water insoluble liquid
fsl
Substances Subject to be Indicated Names
ishl_indicated
Substances Subject to be Notified Names
ishl_notified
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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