Millipore Sigma Vibrant Logo

137002 Citric acid

anhydrous powder EMPROVE® EXPERT Ph Eur,BP,ChP,JP,USP

Citric acid MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: 2-Hydroxypropane-1,2,3-tricarboxylic acid, Hydroxytricarballylic acid

CAS #: 77-92-9 EC Number: 201-069-1 Molar Mass: 192.12 g/mol Chemical Formula: (HOOCCH₂)₂C(OH)COOH Hill Formula: C₆H₈O₇ Grade: Ph Eur,BP,ChP,JP,USP
View This Product on Sigma-Aldrich
137002
View Pricing & Availability
Learn about the Emprove® Program

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar MassGrade Value
77-92-9201-069-1C₆H₈O₇(HOOCCH₂)₂C(OH)COOH192.12 g/molPh Eur,BP,ChP,JP,USP

Pricing & Availability

Catalogue Number AvailabilityPackaging Qty/Pack Price Quantity
1.37002.1000
Retrieving availability...
—
Limited Availability Limited Availability
In Stock 
Discontinued
Limited Quantities Available
Availability to be confirmed
    Remaining : Will advise
      Remaining : Will advise
      Will advise
      Contact Customer Service
      Contact Customer Service

      		 Plastic bottle 1 kg
      Retrieving price...
      Price could not be retrieved
      Minimum Quantity is a multiple of
      Maximum Quantity is
      Upon Order Completion More Information
      You Saved ()
       
      —
      Request Pricing
      		 —
      1.37002.5000
      Retrieving availability...
      —
      Limited Availability Limited Availability
      In Stock 
      Discontinued
      Limited Quantities Available
      Availability to be confirmed
        Remaining : Will advise
          Remaining : Will advise
          Will advise
          Contact Customer Service
          Contact Customer Service

          		 Plastic bottle 5 kg
          Retrieving price...
          Price could not be retrieved
          Minimum Quantity is a multiple of
          Maximum Quantity is
          Upon Order Completion More Information
          You Saved ()
           
          —
          Request Pricing
          		 —
          1.37002.9012
          Retrieving availability...
          —
          Limited Availability Limited Availability
          In Stock 
          Discontinued
          Limited Quantities Available
          Availability to be confirmed
            Remaining : Will advise
              Remaining : Will advise
              Will advise
              Contact Customer Service
              Contact Customer Service

              		 Bucket, plastic 12 kg
              Retrieving price...
              Price could not be retrieved
              Minimum Quantity is a multiple of
              Maximum Quantity is
              Upon Order Completion More Information
              You Saved ()
               
              —
              Request Pricing
              		 —
              1.37002.9029
              Retrieving availability...
              —
              Limited Availability Limited Availability
              In Stock 
              Discontinued
              Limited Quantities Available
              Availability to be confirmed
                Remaining : Will advise
                  Remaining : Will advise
                  Will advise
                  Contact Customer Service
                  Contact Customer Service

                  		 Double PE Sack 25 kg
                  Retrieving price...
                  Price could not be retrieved
                  Minimum Quantity is a multiple of
                  Maximum Quantity is
                  Upon Order Completion More Information
                  You Saved ()
                   
                  —
                  Request Pricing
                  		 —
                  Description
                  Catalogue Number137002
                  Synonyms2-Hydroxypropane-1,2,3-tricarboxylic acid, Hydroxytricarballylic acid
                  DescriptionCitric acid
                  References
                  Product Information
                  CAS number77-92-9
                  EC number201-069-1
                  GradePh Eur,BP,ChP,JP,USP
                  Hill FormulaC₆H₈O₇
                  Chemical formula(HOOCCH₂)₂C(OH)COOH
                  Molar Mass192.12 g/mol
                  HS Code2918 14 00
                  Structure formula ImageStructure formula Image
                  Quality LevelMQ500
                  Applications
                  Biological Information
                  Physicochemical Information
                  Boiling point200 °C (1013 hPa) (decomposition)
                  Density1.67 g/cm3 (20 °C)
                  Melting Point153 °C (decomposition)
                  pH value1.7 (100 g/l, H₂O, 20 °C)
                  Vapor pressure<0.1 hPa (25 °C)
                  Bulk density560 kg/m3
                  Solubility1330 g/l
                  Dimensions
                  Materials Information
                  Toxicological Information
                  LD 50 oralLD50 Rat 3000 mg/kg
                  Safety Information according to GHS
                  Hazard Pictogram(s) Hazard Pictogram(s)
                  Hazard Statement(s)H319: Causes serious eye irritation.
                  H335: May cause respiratory irritation.
                  Precautionary Statement(s)P261: Avoid breathing dust.
                  P264: Wash skin thoroughly after handling.
                  P271: Use only outdoors or in a well-ventilated area.
                  P280: Wear eye protection/ face protection.
                  P304 + P340 + P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
                  P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
                  Signal WordWarning
                  RTECSGE7350000
                  Storage class10 - 13 Other liquids and solids
                  WGKWGK 1 slightly hazardous to water
                  Safety Information
                  Categories of dangerirritant
                  Product Usage Statements
                  Storage and Shipping Information
                  StorageStore at +15°C to +25°C.
                  Packaging Information
                  Transport Information
                  Declaration (railroad and road) ADR, RIDKein Gefahrgut
                  Declaration (transport by air) IATA-DGRNo Dangerous Good
                  Declaration (transport by sea) IMDG-CodeNo Dangerous Good
                  Supplemental Information
                  Specifications
                  Assay (alkalimetric, calculated on anhydrous substance)99.5 - 100.5 %
                  Identity (IR-spectrum)passes test
                  Identity (wet chemistry)passes test
                  Appearancewhite to almost white, fine powder
                  Appearance of solution (200 g/l; water)clear (≤ 1.5 NTU) and not more intense in color than reference solution Y₇, BY₇ or GY₇
                  Chloride (Cl)≤ 5 ppm
                  Sulfate (SO₄)≤ 50 ppm
                  Heavy metals (as Pb)≤ 5 ppm
                  Al (Aluminium)≤ 0.2 ppm
                  As (Arsenic)≤ 1 ppm
                  Ca (Calcium)passes test
                  Oxalates (as C₂H₂O₄)≤ 360 ppm
                  Oxalate (C₂H₂O₄) (ChP)passes test
                  Residual solvents (ICH Q3C)excluded by manufacturing process
                  Readily carbonisable substancepasses test
                  Sulfated ash (600 °C)≤ 0.05 %
                  Water (according to Karl Fischer)≤ 0.5 %
                  Total aerobic microbial count (TAMC)≤ 100 CFU/g
                  Total combined yeasts/moulds count (TYMC)≤ 10 CFU/g
                  Bile-tolerant gram-negative bacteria (absent in 1 g)passes test
                  Candida albicans (absent in 1 g)passes test
                  Escherichia coli (absent in 1 g)passes test
                  Pseudomonas aeruginosa (absent in 1 g)passes test
                  Salmonella (absent in 10 g)passes test
                  Staphylococcus aureus (absent in 1 g)passes test
                  DNases (Exo- and endonucleases)not detectable
                  RNasesnot detectable
                  Bacterial endotoxins< 10

                  Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
                  Corresponds to Ph. Eur., BP, ChP, JP, USP
                  Global Trade Item Number
                  Catalogue Number GTIN
                  1.37002.1000 04027269358235
                  1.37002.5000 04027269061890
                  1.37002.9012 04027269077419
                  1.37002.9029 04027269061418

                  Documentation

                  Material Qualification Dossier

                  TitleVersion
                  9.0

                  Quality Management Dossier (Open Access)

                  Title

                  Operational Excellence Dossier

                  Title

                  Citric acid SDS

                  Title

                  Safety Data Sheet (SDS) 

                  Citric acid Certificates of Analysis

                  Product Number PackagingSpecificationLot Number
                  1.37002.1000 Plastic bottlePDF Specification Document
                  1.37002.5000 Plastic bottlePDF Specification Document
                  1.37002.9012 Bucket, plasticPDF Specification Document
                  1.37002.9029 Double PE SackPDF Specification Document

                  Certificates

                  Title

                  Brochure

                  Title
                  バイオ医薬品製造用製品ガイド