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Merck

1.01740

Barium peroxide

(anhydrous, heavy), Technipur®

Synonym(s):

Barium binoxide, Barium dioxide, Barium superoxide

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About This Item

Empirical Formula (Hill Notation):
BaO2
CAS Number:
Molecular Weight:
169.33
UNSPSC Code:
12352303
NACRES:
NA.21
MDL number:
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Quality Level

pH

12 (20 °C, 10 g/L in H2O, slurry)

mp

450 °C

density

4.96 g/cm3 at 20 °C

SMILES string

[Ba++].[O-][O-]

InChI

1S/Ba.O2/c;1-2/q+2;-2

InChI key

ZJRXSAYFZMGQFP-UHFFFAOYSA-N

General description

Barium peroxide (BaO2) is commonly used as a strong oxidizing agent in chemical industries due to its high reactivity and high storage stability under inert conditions. It is also used in fireworks because it produces a bright green color when ignited.

Application

Barium peroxide can also be used in the synthesis of hexagonal barium ferrite magnets (BaFe12O19) by SHS reaction (self-propagating high-temperature synthesis) in the presence of Fe and Fe2O3. Barium ferrite magnetic components are the most commonly used in a wide range of products, from televisions and computer monitors to kitchen cabinet magnetic clasps.

BaO2 can also be used as a:
  • Bleaching agent in industrial bleach applications.
  • Catalyst to start an aluminothermic reaction.
  • Oxidizer in various pyrotechnic mixtures.
  • Green flare in tracer ammunition.

It can also find application in various other fields such as CO2 adsorption, disinfection, luminol-driven chemiluminescence, and wastewater treatment.

Legal Information

Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

Group 1: Oxidizing solids + Inorganic peroxides + Hazardous rank I + 1st oxidizing solid

fsl



Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Binary and ternary pyrotechnic systems of Mn and/or Mo and BaO2 and/or SrO2: Part 2. Combustion studies
Drennan RL
Thermochimica Acta, 208, 223-246 (1992)
Combustion Synthesis of BaFe12O19 in an External Magnetic Field: Time-Resolved X-ray Diffraction (TRXRD) Studies
Affleck L
Advanced Materials, 12(18) (2000)
Barium Peroxide: a Simple Test Case for First-Principles Investigations on the Temperature Dependence of Solid-State Vibrational Frequencies
Stoffel RP and Dronskowski R
Zeitschrift fur Anorganische und Allgemeine Chemie, 638(10), 1403-1406 (2012)



Global Trade Item Number

SKUGTIN
1.01740.905004022536024318
1.01740.100004022536024301