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106007 Methanol

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar MassGrade Value
67-56-1200-659-6CH₄OCH₃OH32.04 g/molReag. Ph Eur
Description
Catalogue Number106007
SynonymsMeOH, Hydroxymethane, Methyl alcohol, Carbinol
OverviewWith their high degree of UV transmittance, low particle count, low acidity and alkalinity and low evaporation residue level, LiChrosolv® solvents are ideal for reproducible separations. Since separations are normally carried out under gradient conditions in analytical HPLC, we offer solvents in "gradient grade" as well as "isocratic grade". This enables to minimize the gradient effect of the solvent involved.
References
Product Information
CAS number67-56-1
EC index number603-001-00-X
EC number200-659-6
GradeReag. Ph Eur
Hill FormulaCH₄O
Chemical formulaCH₃OH
Molar Mass32.04 g/mol
HS Code2905 11 00
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
ApplicationMethanol gradient grade for liquid chromatography LiChrosolv® Reag. Ph Eur. CAS 67-56-1, chemical formula CH₃OH, molar mass 32.04 g/mol.
Biological Information
Physicochemical Information
Boiling point64.5 °C (1013 hPa)
Density0.792 g/cm3 (20 °C)
Evaporation number1.9
Explosion limit5.5 - 44 %(V)
Flash point9.7 °C
Ignition temperature420 °C DIN 51794
Melting Point-97.8 °C
Vapor pressure128 hPa (20 °C)
Viscosity kinematic0.54 - 0.59 mm2/s (20 °C) no data available
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 5628 mg/kg
LD 50 dermalLD50 Rabbit 17100 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H370: Causes damage to organs.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal WordDanger
RTECSPC1400000
Safety Information
Product Usage Statements
Storage and Shipping Information
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1230 , 3 (6.1), II
Declaration (transport by air) IATA-DGRUN 1230 , 3 (6.1), II
Declaration (transport by sea) IMDG-CodeUN 1230 , 3 (6.1), II
Supplemental Information
Specifications
Purity (GC)≥ 99.9 %
Identity (IR)conforms
Evaporation residue≤ 2.0 mg/l
Water≤ 0.02 %
Color≤ 10 Hazen
Density (d 20 °C/20 °C)0.791 - 0.793
Boiling point64 - 65 °C
Acidity≤ 0.0002 meq/g
Alkalinity≤ 0.0002 meq/g
Gradient grade (at 235 nm)≤ 2.0 mAU
Gradient grade (at 254 nm)≤ 1.0 mAU
Fluorescence (as quinine at 254 nm)≤ 1.0 ppb
Fluorescence (as quinine at 365 nm)≤ 0.5 ppb
Transmission (at 210 nm)≥ 20 %
Transmission (at 220 nm)≥ 60 %
Transmission (at 230 nm)≥ 75 %
Transmission (at 235 nm)≥ 83 %
Transmission (at 250 nm)≥ 95 %
Transmission (from 260 nm)≥ 98 %
Absorbance (at 225 nm)≤ 0.170
Absorbance (at 210 nm)≤ 0.70
Absorbance (at 220 nm)≤ 0.30
Absorbance (at 230 nm)≤ 0.13
Absorbance (at 240 nm)≤ 0.07
Absorbance (at 250 nm)≤ 0.02
Absorbance (from 260 nm)≤ 0.01
Filtered by 0.2 µm filter.
Suitable for UPLC / UHPLC / Ultra HPLC - instruments.
Conforms to Reag. ChP; conforms to Methanol R1 and R2 according to Reag. Ph Eur;
to the requirements of ACS reagent grade for liquid chromatographic suitability.

Documentation

Methanol SDS

Title

Safety Data Sheet (SDS) 

Methanol Certificates of Analysis

Product Number PackagingLot Number
106007

Brochure

Title
Lösungen für regulierte instrumentelle Analyseverfahren
UHPLC 2 - Guidelines for high throughput separations

Technical Info

Title
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Pharmacopoeia Monograph Methods - HPLC and UHPLC methods for Regulated Drug Analysis
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Application Notes

Title
Antifungal medication (Standards) - separation of Itraconazole & impurities - using a Chromolith® HighResolution RP-18e column
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Eye medication (Standards) - separation of Bimatoprost & free acid - using a Chromolith® HighResolution RP-18e column

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Categories

Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Liquid Chromatography, LiChrosolv®
Analytics and Sample Preparation > Analytical Chromatography > Mobile Phases for Chromatography > Solvents for Liquid Chromatography, LiChrosolv®