Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

100563 ortho-Phosphoric acid 85%

Overview

Replacement Information

Key Spec Table

CAS #Grade Value
7664-38-2Ph Eur,BP,ChP,JPE,NF

Products

Catalogue NumberPackaging Qty/Pack
1005631000 Plastic bottle 1 l
1005632500 Plastic bottle 2.5 l
1005635000 Plastic bottle 5 l
1005639025 Plastic container 25 l
Description
Catalogue Number100563
Synonymso-Phosphoric acid, Orthophosphoric acid
References
Product Information
CAS number7664-38-2
GradePh Eur,BP,ChP,JPE,NF
HS Code2809 20 11
Quality LevelMQ500
Applications
Biological Information
Physicochemical Information
Boiling point158 °C (1013 mbar)
Density1.71 g/cm3 (20 °C)
Melting Point21 °C
pH value<0.5 (100 g/l, H₂O, 20 °C)
Vapor pressure2 hPa (20 °C)
Viscosity kinematic30.5 mm2/s (20 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H290: May be corrosive to metals.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)P234: Keep only in original packaging.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
Storage class8B Non-combustible, corrosive hazardous materials
WGKWGK 1 slightly hazardous to water
Disposal12
Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.
Safety Information
Categories of dangercorrosive
Product Usage Statements
Storage and Shipping Information
StorageStore at +2°C to +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1805 , 8, III
Declaration (transport by air) IATA-DGRUN 1805 , 8, III
Declaration (transport by sea) IMDG-CodeUN 1805 , 8, III, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Assay (alkalimetric)85.0 - 88.0 %
Identitypasses test
Specific density (d 20/4)≥ 1.69
Appearance of solutionpasses test
Alkali phosphates, phosphate (JPE)passes test
Volatile acids (as Acetic acid)≤ 0.001
Chloride (Cl)≤ 0.0005 %
Fluoride (F)≤ 0.001
Nitrate (NO₃)≤ 0.0003 %
Nitrate (NF-meth.)passes test
Hypophosphorous and phosphorous acidpasses test
Sulfate (SO₄)≤ 0.005 %
Heavy metals (as Pb)≤ 0.0005 %
As (Arsenic)≤ 0.000019 %
Cd (Cadmium)≤ 0.0001 %
Cu (Copper)≤ 0.002 %
Fe (Iron)≤ 0.0050 %
Hg (Mercury)≤ 0.0001 %
K (Potassium)≤ 0.005 %
Na (Sodium)≤ 0.03 %
Pb (Lead)≤ 0.0001 %
Zn (Zinc)≤ 0.002 %
Residual solvents (ICH Q3C)...excluded by production process
Matter precipitated by ammoniapasses test
Substances reducing permanganate (JPE)passes test
Endotoxins≤ 2.5 I.U./ml
Microbiological purity (Total aerobic microbial count (TAMC))≤ 1E+02 CFU/ml
Microbiological purity (Total yeast and mould count (TYMC))≤ 1E+01 CFU/ml

Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
Corresponds to Ph Eur, BP, ChP, JPE, NF.
Global Trade Item Number
Catalogue Number GTIN
1005631000 04022536007823
1005632500 04022536007847
1005635000 04022536881300
1005639025 04022536007861

Documentation

Material Qualification Dossier

TitleVersion
8.0

Quality Management Dossier (Open Access)

Title

Operational Excellence Dossier

Title

ortho-Phosphoric acid 85% SDS

Title

Safety Data Sheet (SDS) 

ortho-Phosphoric acid 85% Certificates of Analysis

Product Number PackagingSpecificationLot Number
1005631000 Plastic bottlePDF Specification Document
1005632500 Plastic bottlePDF Specification Document
1005635000 Plastic bottlePDF Specification Document
1005639025 Plastic containerPDF Specification Document

Certificates

Title