Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

822321 Phosphorus tribromide

Phosphorus tribromide for synthesis. CAS 7789-60-8, EC Number 232-178-2, chemical formula PBr₃.

Phosphorus tribromide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Phosphorus(III) bromide

CAS #: 7789-60-8 EC Number: 232-178-2 Molar Mass: 270.7 g/mol Chemical Formula: PBr₃ Hill Formula: Br₃P
822321
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
7789-60-8232-178-2Br₃PPBr₃270.7 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8223210250 Glass btl. pl.coat. 250 ml
Description
Catalogue Number822321
SynonymsPhosphorus(III) bromide
DescriptionPhosphorus tribromide
References
Product Information
CAS number7789-60-8
EC index number015-103-00-6
EC number232-178-2
Hill FormulaBr₃P
Chemical formulaPBr₃
Molar Mass270.7 g/mol
HS Code2812 90 00
Quality LevelMQ200
Applications
ApplicationPhosphorus tribromide for synthesis. CAS 7789-60-8, EC Number 232-178-2, chemical formula PBr₃.
Biological Information
Physicochemical Information
Boiling point173 - 175 °C (1013 hPa)
Density2.625 g/cm3 (20 °C)
Melting Point-40 °C
Vapor pressure13 hPa (48 °C)
Refractive Index1.6945 (20 °C, 589 nm)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
EUH014: Reacts violently with water.
Precautionary Statement(s)P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
Storage class8B Non-combustible, corrosive hazardous materials
WGKWGK 1 slightly hazardous to water
Disposal24
Liquid inorganic halides and hydrolysis-sensitive reagents can be carefully stirred dropwise into ice-cool 10% sodium hydroxide solution (Cat. No. 105587) (caution: caustic gases!); container D or E.
Safety Information
Categories of dangercorrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1808 , 8, II
Declaration (transport by air) IATA-DGRUN 1808 , 8, II
Declaration (transport by sea) IMDG-CodeUN 1808 , 8, II, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Assay (argentometric)≥ 98.0 %
Appearance of substance (visual)clear to light turbid
Density (d 20 °C/ 4 °C)2.870 - 2.890
Global Trade Item Number
Catalogue Number GTIN
8223210250 04022536489056

Documentation

Phosphorus tribromide SDS

Title

Safety Data Sheet (SDS) 

Phosphorus tribromide Certificates of Analysis

Product Number PackagingSpecificationLot Number
8223210250 Glass btl. pl.coat.PDF Specification Document

Related Products & Applications

Categories

Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Phosphorous Compounds