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103115 1,4-Dioxane

103115
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
123-91-1204-661-8C₄H₈O₂88.11 g/mol

Products

Catalogue NumberPackaging Qty/Pack
1031151000 Glass bottle 1 l
1031152500 Glass bottle 2.5 l
1031156025 Drum stainl. st. 25 l
1031159191 Steel barrel 190 l
Description
Catalogue Number103115
SynonymsGlycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
OverviewEMPLURA® is our low-cost alternative to high-purity qualities. With EMPLURA® we offer a range of solvents for a plurality of basic applications in non-regulated industries and for less demanding applications, preparative laboratory work and cleaning purposes. EMPLURA® solvents provide adequate specifications with the most important parameters.
References
Product Information
CAS number123-91-1
EC index number603-024-00-5
EC number204-661-8
Hill FormulaC₄H₈O₂
Molar Mass88.11 g/mol
HS Code2932 99 00
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Biological Information
Physicochemical Information
Boiling point101.5 °C (1013 hPa)
Density1.034 g/cm3 (20 °C)
Explosion limit1.7 - 25.2 %(V)
Flash point11 °C
Ignition temperature300 °C
Melting Point11.8 °C
pH value6.0 - 8 (500 g/l, H₂O, 20 °C)
Vapor pressure36 hPa (20 °C)
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 5200 mg/kg
LD 50 dermalLD50 Rabbit 7600 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H350: May cause cancer.
EUH019: May form explosive peroxides.
EUH066: Repeated exposure may cause skin dryness or cracking.
Precautionary Statement(s)P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal WordDanger
RTECSJG8225000
Storage class3 Flammable liquids
WGKWGK 3 highly hazardous to water
Disposal3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety Information
Categories of dangerhighly flammable, irritant, carcinogenic
Product Usage Statements
Storage and Shipping Information
StorageStore at +2°C to +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1165 , 3, II
Declaration (transport by air) IATA-DGRUN 1165 , 3, II
Declaration (transport by sea) IMDG-CodeUN 1165 , 3, II
Supplemental Information
Specifications
Purity (GC)≥ 99.0 %
Identity (IR)conforms
Free acid (as CH₃COOH)≤ 0.01 %
Density (d 20 °C/ 4 °C)1.032 - 1.034
Peroxide (as H₂O₂)≤ 0.005 %
Water≤ 0.1 %
Stabilized with about 25 ppm 2,6-Di-tert-butyl-4-methylphenol (BHT)
Global Trade Item Number
Catalogue Number GTIN
1031151000 04022536040042
1031152500 04022536040066
1031156025 04022536040080
1031159191 04027269047740

Documentation

1,4-Dioxane SDS

Title

Safety Data Sheet (SDS) 

1,4-Dioxane Certificates of Analysis

Product Number PackagingSpecificationLot Number
1031151000 Glass bottlePDF Specification Document
1031152500 Glass bottlePDF Specification Document
1031156025 Drum stainl. st.PDF Specification Document
1031159191 Steel barrelPDF Specification Document

Brochure

Title
Inorganics & Solvents for classical analysis
Safety Connects - Solvents Withdrawal System Brochure

Related Products & Applications

Accessories (Primary)

Catalogue Number Description
101114 Withdrawal system for solvents with manual pressure build-up for 10 l and 25 l drums
106710 Withdrawal system for stainless steel barrels and drums
108803 Drum key
901756 Dip tube
902698 Pressure safety device 0.5 bar
963533 Safety carrier
964205 Reducing valve, 0.2 bar with 2 tube connections 6 x 8 mm and integrated excess pressure safety device 0.5 bar

Accessories (Secondary)

Catalogue Number Description
100801 Label set acc. GHS
107070 Antistatic device
108801 Bottle key
119171 Withdrawal system for solvents

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Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Solvents for Lab Applications EMPLURA®
Reagents, Chemicals and Labware > Solvents > Solvents for Classical Analysis and Synthesis > Solvents for Preparative Lab Applications EMPLURA®
Reagents, Chemicals and Labware > Solvents > Solvents for Production and Purification > Solvents for Lab Applications EMPLURA®