Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

800899 Dimethyl malonate

Dimethyl malonate for synthesis. CAS 108-59-8, chemical formula CH₂(COOCH₃)₂.

Dimethyl malonate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Malonic acid dimethyl ester

CAS #: 108-59-8 EC Number: 203-597-8 Molar Mass: 132.12 g/mol Chemical Formula: CH₂(COOCH₃)₂ Hill Formula: C₅H₈O₄
800899
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
108-59-8203-597-8C₅H₈O₄CH₂(COOCH₃)₂132.12 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8008990100 Glass bottle 100 ml
8008990500 Glass bottle 500 ml
8008991000 Glass bottle 1 l
Description
Catalogue Number800899
SynonymsMalonic acid dimethyl ester
DescriptionDimethyl malonate
References
Product Information
CAS number108-59-8
EC number203-597-8
Hill FormulaC₅H₈O₄
Chemical formulaCH₂(COOCH₃)₂
Molar Mass132.12 g/mol
HS Code2917 19 10
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
ApplicationDimethyl malonate for synthesis. CAS 108-59-8, chemical formula CH₂(COOCH₃)₂.
Biological Information
Physicochemical Information
Boiling point181 - 183 °C (1013 hPa)
Density1.107 g/cm3 (63.4 °C)
Explosion limit1.3 - 17.4 %(V)
Flash point85 °C
Ignition temperature440 °C
Melting Point-62 °C
Vapor pressure1013.25 hPa (180.7 °C)
Solubility140.7 - 143.3 g/l slightly soluble
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 5331 mg/kg
LD 50 dermalLD50 Rabbit > 5000 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Statement(s)H319: Causes serious eye irritation.
Precautionary Statement(s)P264: Wash skin thoroughly after handling.
P280: Wear eye protection/ face protection.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313: If eye irritation persists: Get medical advice/ attention.
Signal WordWarning
RTECSOO0950000
Storage class10 - 13 Other liquids and solids
WGKWGK 1 slightly hazardous to water
Disposal3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety Information
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Supplemental Information
Specifications
Assay (GC, area%)≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C)1.151 - 1.155
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8008990100 04022536364117
8008990500 04022536364124
8008991000 04022536364131

Related Products & Applications

Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Carboxylic Acid Derivatives > Esters of Carboxylic Acid > Esters of Di- and Tricarboxylic Acids
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Carboxylic Acid Derivatives > Esters of Carboxylic Acid > Esters of Di- and Tricarboxylic Acids
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Polyaddition Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Polycondensation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Polyaddition Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Polycondensation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Carboxylic Acid Derivatives > Esters of Carboxylic Acid > Esters of Di- and Tricarboxylic Acids