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824429 (4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2- dimethyl-1,3-dioxolane

824429
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Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
37002-48-5253-307-9C₃₁H₃₂O₂P₂498.55 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8244290500 Glass bottle 500 mg
Description
Catalogue Number824429
Synonyms(+)-DIOP, (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)-butane, (+)-1,4-Bis(diphenylphosphino)-1,4-dideoxy-2,3-O-isopropylidene-D-threitol
References
Product Information
CAS number37002-48-5
EC number253-307-9
Hill FormulaC₃₁H₃₂O₂P₂
Molar Mass498.55 g/mol
HS Code2932 99 00
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
Application(4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2- dimethyl-1,3-dioxolane for synthesis. CAS 37002-48-5, molar mass 498.54 g/mol.
Biological Information
Physicochemical Information
Melting Point86 - 89 °C
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Statement(s)H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
Precautionary Statement(s)P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264: Wash skin thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/ eye protection/ face protection.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordWarning
Storage class10 - 13 Other liquids and solids
WGKWGK 3 highly hazardous to water
Disposal3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety Information
Categories of dangerirritant
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Supplemental Information
Specifications
Assay (HPLC, area%)≥ 95.0 % (a/a)
Melting range (lower value)≥ 87 °C
Melting range (upper value)≤ 91 °C
Spec. rotation [α²0/D (c=2 in benzene)+11.5 - +13.5 °
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8244290500 04022536492322

Documentation

(4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2- dimethyl-1,3-dioxolane SDS

Title

Safety Data Sheet (SDS) 

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Categories

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Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Ketones > Ketales
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Catalysts > Catalysts, Ligands
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Catalysts for Pharma > Catalysts for Enantioselective Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Ketones > Ketales
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Enantioselective Synthesis > Catalysts for Enantioselective Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Enantioselective Synthesis > Catalysts for Enantioselective Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Catalysts for Pharma > Catalysts, Ligands
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Products for Enantioselective Synthesis > Catalysts for Enantioselective Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Catalysts > Catalysts for Enantioselective Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Catalysts > Catalysts, Ligands
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Catalysts > Catalysts for Enantioselective Synthesis