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814109 Tributyltin hydride (stabilized)

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
688-73-3211-704-4C₁₂H₂₈Sn291.05 g/mol

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8141090025
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      Glass bottle 25 ml
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      Description
      Catalogue Number814109
      SynonymsTributylstannane
      References
      Product Information
      CAS number688-73-3
      EC index number050-008-00-3
      EC number211-704-4
      Hill FormulaC₁₂H₂₈Sn
      Molar Mass291.05 g/mol
      HS Code2931 20 00
      Structure formula ImageStructure formula Image
      Quality LevelMQ200
      Applications
      ApplicationTributyltin hydride for synthesis. CAS 688-73-3, molar mass 291.06 g/mol.
      Biological Information
      Physicochemical Information
      Boiling point112 - 114 °C (11 hPa)
      Density1.08 - 1.10 g/cm3 (20 °C)
      Flash point40 °C
      Ignition temperature>250 °C
      Vapor pressure5 hPa (20 °C)
      Dimensions
      Materials Information
      Toxicological Information
      Safety Information according to GHS
      Hazard Pictogram(s) Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Statement(s)H226: Flammable liquid and vapour.
      H301: Toxic if swallowed.
      H312: Harmful in contact with skin.
      H315: Causes skin irritation.
      H319: Causes serious eye irritation.
      H360FD: May damage fertility. May damage the unborn child.
      H372: Causes damage to organs through prolonged or repeated exposure.
      H410: Very toxic to aquatic life with long lasting effects.
      Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
      P273: Avoid release to the environment.
      P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
      P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
      P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
      P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
      Signal WordDanger
      RTECSWH8675000
      Storage class3 Flammable liquids
      WGKWGK 3 highly hazardous to water
      Disposal26
      Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
      Safety Information
      Categories of dangertoxic, irritant, dangerous for the environment
      Product Usage Statements
      Storage and Shipping Information
      StorageStore below +30°C.
      Packaging Information
      Transport Information
      Declaration (railroad and road) ADR, RIDUN 2788 , 6.1, III
      Declaration (transport by air) IATA-DGRUN 2788 , 6.1, III
      Declaration (transport by sea) IMDG-CodeUN 2788 , 6.1, III, Marine Pollutant: P
      Supplemental Information
      Specifications
      Assay (GC, area%)≥ 97.0 % (a/a)
      Density (d 20 °C/ 4 °C)1.096 - 1.102
      Identity (IR)passes test
      The material is stabilised with Butylhydroxytoluene (BHT).
      At time of analytical testing a content of >300 ppm stabiliser was determined.
      Global Trade Item Number
      Catalogue Number GTIN
      8141090025 04022536407012

      Documentation

      Tributyltin hydride (stabilized) SDS

      Title

      Safety Data Sheet (SDS) 

      Tributyltin hydride (stabilized) Certificates of Analysis

      Product Number PackagingSpecificationLot Number
      8141090025 Glass bottlePDF Specification Document

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      Categories

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      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reduction Reagents
      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reduction Reagents
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Organometal Compounds