Millipore Sigma Vibrant Logo

106007 Methanol

Methanol gradient grade for liquid chromatography LiChrosolv® Reag. Ph Eur. CAS 67-56-1, chemical formula CH₃OH, molar mass 32.04 g/mol.

Methanol MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: MeOH, Hydroxymethane, Methyl alcohol, Carbinol

CAS #: 67-56-1 EC Number: 200-659-6 Molar Mass: 32.04 g/mol Chemical Formula: CH₃OH Hill Formula: CH₄O Grade: Reag. Ph Eur
View Products on Sigmaaldrich.com
106007
View Pricing & Availability

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar MassGrade Value
67-56-1200-659-6CH₄OCH₃OH32.04 g/molReag. Ph Eur

Pricing & Availability

Catalogue Number AvailabilityPackaging Qty/Pack Price Quantity
1060071000
Retrieving availability...
—
Limited Availability Limited Availability
In Stock 
Discontinued
Limited Quantities Available
Availability to be confirmed
    Remaining : Will advise
      Remaining : Will advise
      Will advise
      Contact Customer Service
      Contact Customer Service

      		 Glass bottle 1 l
      Retrieving price...
      Price could not be retrieved
      Minimum Quantity is a multiple of
      Maximum Quantity is
      Upon Order Completion More Information
      You Saved ()
       
      —
      Request Pricing
      		 —
      1060072500
      Retrieving availability...
      —
      Limited Availability Limited Availability
      In Stock 
      Discontinued
      Limited Quantities Available
      Availability to be confirmed
        Remaining : Will advise
          Remaining : Will advise
          Will advise
          Contact Customer Service
          Contact Customer Service

          		 Glass bottle 2.5 l
          Retrieving price...
          Price could not be retrieved
          Minimum Quantity is a multiple of
          Maximum Quantity is
          Upon Order Completion More Information
          You Saved ()
           
          —
          Request Pricing
          		 —
          1060074000
          Retrieving availability...
          —
          Limited Availability Limited Availability
          In Stock 
          Discontinued
          Limited Quantities Available
          Availability to be confirmed
            Remaining : Will advise
              Remaining : Will advise
              Will advise
              Contact Customer Service
              Contact Customer Service

              		 Glass bottle 4 l
              Retrieving price...
              Price could not be retrieved
              Minimum Quantity is a multiple of
              Maximum Quantity is
              Upon Order Completion More Information
              You Saved ()
               
              —
              Request Pricing
              		 —
              Description
              Catalogue Number106007
              SynonymsMeOH, Hydroxymethane, Methyl alcohol, Carbinol
              OverviewWith their high degree of UV transmittance, low particle count, low acidity and alkalinity and low evaporation residue level, LiChrosolv® solvents are ideal for reproducible separations. Since separations are normally carried out under gradient conditions in analytical HPLC, we offer solvents in "gradient grade" as well as "isocratic grade". This enables to minimize the gradient effect of the solvent involved.
              References
              Product Information
              CAS number67-56-1
              EC index number603-001-00-X
              EC number200-659-6
              GradeReag. Ph Eur
              Hill FormulaCH₄O
              Chemical formulaCH₃OH
              Molar Mass32.04 g/mol
              HS Code2905 11 00
              Structure formula ImageStructure formula Image
              Quality LevelMQ200
              Applications
              ApplicationMethanol gradient grade for liquid chromatography LiChrosolv® Reag. Ph Eur. CAS 67-56-1, chemical formula CH₃OH, molar mass 32.04 g/mol.
              Biological Information
              Physicochemical Information
              Boiling point64.5 °C (1013 hPa)
              Density0.792 g/cm3 (20 °C)
              Evaporation number1.9
              Explosion limit5.5 - 44 %(V)
              Flash point9.7 °C
              Ignition temperature420 °C DIN 51794
              Melting Point-97.8 °C
              Vapor pressure128 hPa (20 °C)
              Viscosity kinematic0.54 - 0.59 mm2/s (20 °C) no data available
              Dimensions
              Materials Information
              Toxicological Information
              LD 50 oralLD50 Rat 5628 mg/kg
              LD 50 dermalLD50 Rabbit 17100 mg/kg
              Safety Information according to GHS
              Hazard Pictogram(s) Hazard Pictogram(s)
              Hazard Pictogram(s)
              Hazard Pictogram(s)
              Hazard Statement(s)H225: Highly flammable liquid and vapour.
              H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
              H370: Causes damage to organs.
              Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
              P233: Keep container tightly closed.
              P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
              P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
              P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
              P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
              P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
              Signal WordDanger
              RTECSPC1400000
              Storage class3 Flammable liquids
              WGKWGK 2 obviously hazardous to water
              Disposal1
              Strongly contaminated halogen-free organic solvents: container A.
              Safety Information
              Categories of dangerhighly flammable, toxic
              Product Usage Statements
              Storage and Shipping Information
              StorageStore at +2°C to +30°C.
              Packaging Information
              Transport Information
              Declaration (railroad and road) ADR, RIDUN 1230 , 3 (6.1), II
              Declaration (transport by air) IATA-DGRUN 1230 , 3 (6.1), II
              Declaration (transport by sea) IMDG-CodeUN 1230 , 3 (6.1), II
              Supplemental Information
              Specifications
              Purity (GC)≥ 99.9 %
              Identity (IR)conforms
              Evaporation residue≤ 2.0 mg/l
              Water≤ 0.02 %
              Color≤ 10 Hazen
              Density (d 20 °C/20 °C)0.791 - 0.793
              Boiling point64 - 65 °C
              Acidity≤ 0.0002 meq/g
              Alkalinity≤ 0.0002 meq/g
              Gradient grade (at 235 nm)≤ 2.0 mAU
              Gradient grade (at 254 nm)≤ 1.0 mAU
              Fluorescence (as quinine at 254 nm)≤ 1.0 ppb
              Fluorescence (as quinine at 365 nm)≤ 0.5 ppb
              Transmission (at 210 nm)≥ 20 %
              Transmission (at 220 nm)≥ 60 %
              Transmission (at 230 nm)≥ 75 %
              Transmission (at 235 nm)≥ 83 %
              Transmission (at 250 nm)≥ 95 %
              Transmission (from 260 nm)≥ 98 %
              Absorbance (at 225 nm)≤ 0.170
              Filtered by 0.2 µm filter.
              Suitable for UPLC / UHPLC /Ultra HPLC - instruments.
              Conforms to Methanol R1 and R2 according to Reag. Ph Eur;
              conforms to the requirements of ACS for liquid chromatography suitability.
              Global Trade Item Number
              Catalogue Number GTIN
              1060071000 04022536071060
              1060072500 04022536071084
              1060074000 04022536658285

              Documentation

              Methanol SDS

              Title

              Safety Data Sheet (SDS) 

              Methanol Certificates of Analysis

              Product Number PackagingSpecificationLot Number
              1060071000 Glass bottlePDF Specification Document
              1060072500 Glass bottlePDF Specification Document
              1060074000 Glass bottlePDF Specification Document

              Brochure

              Title
              Soluciones para métodos regulados de análisis instrumental
              Solutions for regulated Instrumental Analysis Methods
              UHPLC 2 - Guidelines for high throughput separations

              Technical Info

              Title
              Atovaquone Oral Suspension (USP)
              Complete Monograph Methods - Solutions for regulated Pharmaceutical Instrumental Analysis Methods with HPLC, FTIR, KF, AAS and ICP 2015 -1
              Constituents and Additives - Colorants
              Food Safety and Food Quality Control - Beat your own record!
              Pantoprazole Sodium - USP Method Pantoprazole Sodium RS - USP Method Pantoprazole Sodium Assay
              Pharmaceutical impurity profiling Application guide
              Pharmacopoeia Monograph Methods - HPLC and UHPLC methods for Regulated Drug Analysis
              Traditional Eastern Medication Application guide

              Application Notes

              Title
              Antifungal medication (Standards) - separation of Itraconazole & impurities - using a Chromolith® HighResolution RP-18e column
              Energy Drink - separation of Acesulfame K, Saccharin, Benzoic acid and Caffeine - using a Chromolith® HighResolution RP-18e column
              Eye medication (Standards) - separation of Bimatoprost & free acid - using a Chromolith® HighResolution RP-18e column

              Related Products & Applications

              Accessories (Primary)

              Catalogue Number Description  
              101123 Withdrawal system for solvents Show Pricing & Availability
              106710 Withdrawal system for stainless steel barrels and drums Show Pricing & Availability
              108803 Drum key Show Pricing & Availability
              109996 Adapter S 40 Show Pricing & Availability
              963533 Safety carrier Show Pricing & Availability
              964205 Reducing valve, 0.2 bar with 2 tube connections 6 x 8 mm and integrated excess pressure safety device 0.5 bar Show Pricing & Availability

              Accessories (Secondary)

              Catalogue Number Description  
              100801 Label set acc. GHS Show Pricing & Availability
              103830 HPLC-bottle adapter with 3 tube connections ID 3.2 mm, solvents supply Show Pricing & Availability
              103831 HPLC bottle adapter S40 with 3 tube connections and 1 connection for exhaust air filter, solvents disposal Show Pricing & Availability
              103833 Exhaust air filter for HPLC bottle adapter S40, disposal Show Pricing & Availability
              107070 Antistatic device Show Pricing & Availability
              108801 Bottle key Show Pricing & Availability

              Related Products By: Application Facete

              LC Liquid Chromatography
              Gradient Elution
              UHPLC Ultra High Performance Chromatography
              HPLC High Performance Liquid Chromatography

              Related Products By: Brand Facete

              LiChrosolv®

              Categories

              Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Liquid Chromatography, LiChrosolv®
              Analytics and Sample Preparation > Analytical Chromatography > Mobile Phases for Chromatography > Solvents for Liquid Chromatography, LiChrosolv®