Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

108262 Trifluoroacetic acid

Trifluoroacetic acid for spectroscopy Uvasol®. CAS 76-05-1, EC Number 200-929-3, chemical formula CF₃COOH.

Trifluoroacetic acid MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: TFA, TFA

CAS #: 76-05-1 EC Number: 200-929-3 Molar Mass: 114.02 g/mol Chemical Formula: CF₃COOH Hill Formula: C₂HF₃O₂
108262
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
76-05-1200-929-3C₂HF₃O₂CF₃COOH114.02 g/mol

Products

Catalogue NumberPackaging Qty/Pack
1.08262.0025 Glass bottle 25 ml
1.08262.0100 Glass bottle 100 ml
1.08262.1000 Glass bottle 1 l
1.08262.2500 Glass bottle 2.5 l
Description
Catalogue Number108262
SynonymsTFA, TFA
DescriptionTrifluoroacetic acid
OverviewAccurate analytic results in UV/VIS and infrared spectroscopy depend on the use of very pure solvents for sample preparation. The Uvasol® solvents range has been specially designed for spectroscopy and other applications requiring solvents of the highest spectral purity. The refinement process allows a greater degree of security in applications and avoids misinterpretation of analytical results caused by traces of UV, IR and fluorescence contamination. Uvasol® solvents offer best UV transmittance. In all specifications the minimum transmittance for 5 typical wavelengths are identified.
References
Product Information
CAS number76-05-1
EC index number607-091-00-1
EC number200-929-3
Hill FormulaC₂HF₃O₂
Chemical formulaCF₃COOH
Molar Mass114.02 g/mol
HS Code2915 90 90
Structure formula ImageStructure formula Image
Quality LevelMQ100
Applications
ApplicationTrifluoroacetic acid for spectroscopy Uvasol®. CAS 76-05-1, EC Number 200-929-3, chemical formula CF₃COOH.
Biological Information
Physicochemical Information
Boiling point72 °C (1013 hPa)
Density1.48 g/cm3
Flash point>100 °C not determinable
Melting Point-15.2 °C
pH value1 (10 g/l, H₂O)
Vapor pressure158 hPa (25 °C)
Solubility10 g/cm3 soluble
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s)P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
RTECSAJ9625000
Storage class8A Combustible, corrosive hazardous materials
WGKWGK 2 obviously hazardous to water
Disposal4
Liquid organic acids or solutions should be diluted, if necessary, and carefully neutralized with sodium hydrogen carbonate (Cat. No. 106323) or with sodium hydroxide (Cat. No 106462). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535).
Safety Information
Categories of dangerharmful, corrosive, dangerous for the environment
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2699 , 8, I
Declaration (transport by air) IATA-DGRUN 2699 , 8, I
Declaration (transport by sea) IMDG-CodeUN 2699 , 8, I, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Assay (acidimetric)≥ 99.8 %
Water (K. F.)≤ 0.10 %
Color number (Apha)≤ 10
Evaporation residue≤ 0.005 %
UV-transmission (at 265 nm)≥ 10.0 %
UV-transmission (at 305 nm)≥ 50.0 %
UV-transmission (at 320 nm)≥ 80.0 %
UV-transmission (from 325 nm)≥ 90.0 %
Global Trade Item Number
Catalogue Number GTIN
1.08262.0025 04022536102061
1.08262.0100 04022536102078
1.08262.1000 04027269048921
1.08262.2500 04027269167028

Documentation

Trifluoroacetic acid SDS

Title

Safety Data Sheet (SDS) 

Trifluoroacetic acid Certificates of Analysis

Product Number PackagingSpecificationLot Number
1.08262.0025 Glass bottlePDF Specification Document
1.08262.0100 Glass bottlePDF Specification Document
1.08262.1000 Glass bottlePDF Specification Document
1.08262.2500 Glass bottlePDF Specification Document

Technical Info

Title
Complete Monograph Methods - Solutions for regulated Pharmaceutical Instrumental Analysis Methods with HPLC, FTIR, KF, AAS and ICP 2015 -1

Related Products & Applications

Accessories (Secondary)

Catalogue Number Description
100801 Label set acc. GHS
108801 Bottle key
963533 Safety carrier

Related Products By: Application Facete

IR Spectroscopy
UV/Vis Spectroscopy

Related Products By: Brand Facete

Uvasol®

Categories

Analytics and Sample Preparation > Spectroscopy > Solvents for Spectroscopy, Uvasol®
Reagents, Chemicals and Labware > Solvents > Solvents for Instrumental Organic Analysis > Solvents for Spectroscopy, Uvasol®
Analytics and Sample Preparation > Spectroscopy > UV/VIS Spectroscopy > Solvents for UV/VIS Spectroscopy