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111587 Potassium hydroxide solution in methanol

111587
Purchase on Sigma-Aldrich

Overview

Replacement Information
Replacement InformationIn North America 111587.1000 replaces PX1498A-6 with a very similar specification
In North America 111587.1000 replaces PX1498A-3 with a very similar specification but a different pack size

Products

Catalogue NumberPackaging Qty/Pack
1.11587.1000 Glass bottle 1 l
1.11587.1003 Glass bottle 1 l
Description
Catalogue Number111587
ReplacesPX1498A-6; PX1498A-3
References
Product Information
HS Code3822 90 00
Quality LevelMQ200
Applications
ApplicationPotassium hydroxide solution in methanol c(KOH) = 0.1 mol/l (0.1 N) Titripur®. Potassium hydroxide solution in methanol HS Code 3822 00 00, ph value 13.5 (H₂O, 20 °C).
Biological Information
Physicochemical Information
Density0.80 g/cm3 (20 °C)
Explosion limit5.5 - 44 %(V) Methanol
Flash point7 °C
Ignition temperature455 °C Methanol
pH value13.5 (H₂O, 20 °C)
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H290: May be corrosive to metals.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H370: Causes damage to organs.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal WordDanger
Storage class3 Flammable liquids
WGKWGK 2 obviously hazardous to water
Disposal1
Strongly contaminated halogen-free organic solvents: container A.
Safety Information
Categories of dangerhighly flammable, toxic, irritant
Product Usage Statements
Storage and Shipping Information
StorageStore at +15°C to +25°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 3286 , 3 (6.1, 8), II
Declaration (transport by air) IATA-DGRUN 3286 , 3 (6.1, 8), II
Declaration (transport by sea) IMDG-CodeUN 3286 , 3 (6.1, 8), II, Segregation Group: 18 (Alkalis)
Supplemental Information
Specifications
Formliquid
Amount-of-substance concentration0.0995 - 0.1005 mol/l
Measurement uncertainty+/- 0.0003
TraceabilityNIST SRM
The amount-of-substance concentration of this volumetric solution is analyzed by our quality control laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025.
The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 84 potassium hydrogen phthalate) by means of volumetric standard potassium hydrogen phthalate (article number 1.02400), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.
Note: The titer is a correction factor to correct for variations of the volumetric solution, the titration equipment, the temperature and other laboratory conditions. For correct titration results it is recommended to determine a titer with the laboratory specific equipment and under laboratory specific conditions directly after opening a new bottle and at regular time intervals.
Global Trade Item Number
Catalogue Number GTIN
1.11587.1000 04027269029487
1.11587.1003 04054839999758