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811866 Crown ether/Dicyclohexyl-18-crown-6

811866
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
16069-36-6240-216-4C₂₀H₃₆O₆372.5 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8.11866.0001 Glass bottle 1 g
8.11866.0005 Glass bottle 5 g
Description
Catalogue Number811866
Synonyms2,5,8,15,18,21-Hexaoxatricyclo[20.4.0.09.14] hexacosane, Dicyclohexyl-18-crown-6
References
Product Information
CAS number16069-36-6
EC number240-216-4
Hill FormulaC₂₀H₃₆O₆
Molar Mass372.5 g/mol
HS Code2932 99 99
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
ApplicationCrown ether/Dicyclohexyl-18-crown-6 (mixture of cis- and trans-isomers) for synthesis. CAS 16069-36-6, molar mass 372.51 g/mol.
Biological Information
Physicochemical Information
Flash point113 °C
Melting Point47 °C
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 176 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Statement(s)H301: Toxic if swallowed.
H319: Causes serious eye irritation.
Precautionary Statement(s)P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear eye protection/ face protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313: If eye irritation persists: Get medical advice/ attention.
Signal WordDanger
RTECSHP5385000
Storage class6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 1 slightly hazardous to water
Disposal9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Safety Information
Categories of dangertoxic
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2811 , 6.1, III
Declaration (transport by air) IATA-DGRUN 2811 , 6.1, III
Declaration (transport by sea) IMDG-CodeUN 2811 , 6.1, III
Supplemental Information
Specifications
Assay (GC, area%)≥ 97.0 % (a/a)
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8.11866.0001 04022536403854
8.11866.0005 04022536403861

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Categories

Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Ethers > Crown Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Ethers > Crown Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Catalysts for Pharma
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Catalysts
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Catalysts
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Ethers > Crown Compounds