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818044 Lithium

818044
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Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
7439-93-2231-102-5Li6.94 g/mol

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      Glass bottle 50 g
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      8180449999
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          Description
          Catalogue Number818044
          DescriptionLithium
          References
          Product Information
          CAS number7439-93-2
          EC index number003-001-00-4
          EC number231-102-5
          Hill FormulaLi
          Molar Mass6.94 g/mol
          HS Code2805 19 90
          Quality LevelMQ200
          Applications
          ApplicationLithium (granular) (protective medium: argon) for synthesis. CAS 7439-93-2, EC Number 231-102-5, chemical formula Li.
          Biological Information
          Physicochemical Information
          Density0.534 g/cm3
          Melting Point180 °C
          Vapor pressure1 hPa (723 °C)
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H260: In contact with water releases flammable gases which may ignite spontaneously.
          H314: Causes severe skin burns and eye damage.
          EUH014: Reacts violently with water.
          Precautionary Statement(s)P223: Do not allow contact with water.
          P231 + P232: Handle and store contents under inert gas. Protect from moisture.
          P260: Do not breathe dust.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P402 + P404: Store in a dry place. Store in a closed container.
          Signal WordDanger
          Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
          WGKWGK 1 slightly hazardous to water
          Disposal26
          Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
          Safety Information
          Categories of dangerhighly flammable, corrosive
          Product Usage Statements
          Storage and Shipping Information
          StorageStore below +30°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 1415 , 4.3, I
          Declaration (transport by air) IATA-DGRUN 1415 , 4.3, I
          Declaration (transport by sea) IMDG-CodeUN 1415 , 4.3, I
          Supplemental Information
          Specifications
          Assay of Li≥ 99.0 %
          Global Trade Item Number
          Catalogue Number GTIN
          8180440050 04022536426617
          8180449999 04027269221058