Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

814324 Bromotrimethylsilane

814324
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
2857-97-8220-672-0C₃H₉BrSi(CH₃)₃SiBr153.1 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8143240010 Glass bottle 10 ml
8143240100 Glass bottle 100 ml
Description
Catalogue Number814324
SynonymsTrimethylbromosilane, Trimethylsilyl bromide, TMB, TMBS
References
Product Information
CAS number2857-97-8
EC number220-672-0
Hill FormulaC₃H₉BrSi
Chemical formula(CH₃)₃SiBr
Molar Mass153.1 g/mol
HS Code2931 90 00
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
ApplicationBromotrimethylsilane for synthesis. CAS No. 2857-97-8, EC Number 220-672-0.
Biological Information
Physicochemical Information
Boiling point79 °C (1013 hPa)
Density1.172 g/cm3 (25 °C)
Flash point-12 °C
Melting Point-44 °C
Dimensions
Materials Information
Toxicological Information
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
EUH014: Reacts violently with water.
Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
Storage class3 Flammable liquids
WGKWGK 3 highly hazardous to water
Disposal24
Liquid inorganic halides and hydrolysis-sensitive reagents can be carefully stirred dropwise into ice-cool 10% sodium hydroxide solution (Cat. No. 105587) (caution: caustic gases!); container D or E.
Safety Information
Categories of dangerflammable, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2924 , 3 (8), II
Declaration (transport by air) IATA-DGRUN 2924 , 3 (8), II
Declaration (transport by sea) IMDG-CodeUN 2924 , 3 (8), II, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Assay (argentometric)≥ 98.0 %
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8143240010 04022536411972
8143240100 04027269055783

Related Products & Applications

Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Silylation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Silicium Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Silicium Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Halogenation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Halogenation Reagents
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Silicium Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Silylation Reagents